Editor’s Choice Articles

Editor’s Choice articles are based on recommendations by the scientific editors of MDPI journals from around the world. Editors select a small number of articles recently published in the journal that they believe will be particularly interesting to readers, or important in the respective research area. The aim is to provide a snapshot of some of the most exciting work published in the various research areas of the journal.

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18 pages, 3054 KB  
Article
Integrating Local and Global Features for Wafer Defect Pattern Classification via Sequential Hybrid Architecture
by Jaeho Song, Seungmin Oh, Juhyeon Noh, Minsoo Hahn and Jinsul Kim
Processes 2026, 14(7), 1134; https://doi.org/10.3390/pr14071134 - 31 Mar 2026
Viewed by 514
Abstract
Wafer map defect pattern classification supports quality monitoring in semiconductor manufacturing, but public benchmark datasets such as WM-811K exhibit extreme class imbalance, where majority classes can dominate standard metrics. This study aims to improve minority class performance while maintaining inference efficiency. Building on [...] Read more.
Wafer map defect pattern classification supports quality monitoring in semiconductor manufacturing, but public benchmark datasets such as WM-811K exhibit extreme class imbalance, where majority classes can dominate standard metrics. This study aims to improve minority class performance while maintaining inference efficiency. Building on an iFormer-based hybrid backbone, we propose the Pattern-Selective Sequential Hybrid Network (PSS-HNet), which redesigns attention blocks to sequentially integrate local interaction (Modulated Convolution) and global interaction (Modulated Axial Attention) and applies sigmoid-based gating to control contextual information injection. Experiments on WM-811K (9 classes) compare iFormer (baseline), Axial-only, Axial+Modulation, and PSS-HNet using macro-averaged metrics as primary indicators, along with class-wise analysis and efficiency evaluation. PSS-HNet improves Macro-Recall by 1.02 percentage points (from 0.8852 to 0.8954) and Macro-F1 by 0.54 percentage points (from 0.9044 to 0.9098) over the baseline while maintaining similar accuracy. It also reduces computational cost and inference latency to 0.754 G FLOPs, 4.381 M parameters, and 7.682 ms, compared with 1.103 G FLOPs, 6.245 M parameters, and 8.666 ms for the baseline. Overall, selective sequential local–global integration provides a favorable balance between minority class performance and efficiency. Full article
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24 pages, 7491 KB  
Article
Recycling Expanded Polystyrene Waste into Microfibers by Air Jet Spinning Using a Partially Bio-Based D-Limonene Solvent System
by Javier Mauricio Anaya-Mancipe, Raissa de Oliveira Santos da Cruz, Douglas Gama Caetano, Marysilvia Ferreira da Costa and Hector Guillermo Kotik
Processes 2026, 14(7), 1106; https://doi.org/10.3390/pr14071106 - 29 Mar 2026
Viewed by 746
Abstract
Expanded polystyrene (EPS) waste poses a major environmental concern due to its high volume, low density, and resistance to biodegradation. In this study, post-consumer EPS was reprocessed into continuous microfibers by Air Jet Spinning (AJS) using chloroform and chloroform/D-limonene as solvent systems. The [...] Read more.
Expanded polystyrene (EPS) waste poses a major environmental concern due to its high volume, low density, and resistance to biodegradation. In this study, post-consumer EPS was reprocessed into continuous microfibers by Air Jet Spinning (AJS) using chloroform and chloroform/D-limonene as solvent systems. The effects of polymer concentration, air pressure, and solvent ratio on fiber formation were systematically investigated through rheological and surface tension analyses. The incorporation of 10 vol. % D-limonene improved jet stability and reduced bead formation, attributed to its lower volatility and favorable solubility with EPS, as supported by Hansen solubility parameters. SEM analysis confirmed uniform microfiber formation within a defined processing window. FTIR spectra indicated preservation of the polystyrene chemical structure, while TGA and DSC analyses were used to evaluate thermal behavior and assess potential residual solvent retention, particularly related to D-limonene. The results elucidate the interplay between solvent volatility, solution properties, and fiber morphology, establishing a sustainable processing framework for converting EPS waste into value-added fibrous materials via AJS. This work contributes to the United National Sustainable Development Goals, particularly SDG 12 (Responsible Consumption and Production) by promoting EPS waste valorization, and SDG 13 (Climate Action) through the partial replacement of conventional solvents with sustainable alternative. Full article
(This article belongs to the Special Issue Polymer Nanocomposites for Smart Applications)
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19 pages, 3985 KB  
Article
Optimization of Particle Size Blending and Binder Content in Coconut Shell-Based Activated Carbon Monoliths for Methane Adsorption
by Jun Hyung Jho, Hyun Ku Lee, Min Seong Han and Byong Chol Bai
Processes 2026, 14(7), 1029; https://doi.org/10.3390/pr14071029 - 24 Mar 2026
Viewed by 429
Abstract
This study examined the effects of particle size blending and hybrid binder content on the structural properties and methane adsorption behavior of coconut shell-based activated carbon monoliths. Monoliths were prepared using activated carbon particles with two size ranges (212–250 µm and 26–53 µm), [...] Read more.
This study examined the effects of particle size blending and hybrid binder content on the structural properties and methane adsorption behavior of coconut shell-based activated carbon monoliths. Monoliths were prepared using activated carbon particles with two size ranges (212–250 µm and 26–53 µm), blending ratios of 1:9, 3:7, 5:5, and 7:3, and a hybrid binder containing styrene–butyl acrylate (SBA) and carboxymethylcellulose (CMC). Morphology and elemental composition were analyzed by SEM-EDS, specific surface area and pore structure were evaluated by BET analysis, and surface properties were examined by XPS. Structural density and compressive strength were also measured. Among the tested samples, M50ML showed the highest structural density (0.544 g/cm3), compressive strength (27.5 MPa), and methane uptake (3.06 mg/g). This result was related to improved packing by particle size blending while maintaining microporosity. These results indicate that particle size blending and binder content significantly affected the structural properties and methane adsorption behavior of the prepared monoliths. Full article
(This article belongs to the Special Issue Optimization and Analysis of Energy System)
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20 pages, 266 KB  
Article
The Influence of Traditional and Industrial Smoking Technologies on the Physicochemical Properties, Color, and Texture of Traditional Meat Products
by Krešimir Mastanjević, Leona Puljić, Silvio Halt, Brankica Kartalović, Dragan Kovačević and Kristina Habschied
Processes 2026, 14(6), 1018; https://doi.org/10.3390/pr14061018 - 22 Mar 2026
Viewed by 662
Abstract
The aim of this study is to evaluate the influence of traditional and industrial smoking technologies on the physicochemical properties, color, texture, and mass loss of selected cured pork products. Four products (dry-cured pork neck, dry-cured pork loin, pancetta, and fermented sausages in [...] Read more.
The aim of this study is to evaluate the influence of traditional and industrial smoking technologies on the physicochemical properties, color, texture, and mass loss of selected cured pork products. Four products (dry-cured pork neck, dry-cured pork loin, pancetta, and fermented sausages in natural and collagen casings) were produced using two smoking regimes (traditional and industrial). The samples were analyzed at two processing stages, after smoking and at the end of the production process. Physicochemical composition, pH, water activity (aw), color parameters (CIE L*a*b*), texture profile parameters, and mass loss were determined using standard analytical methods. Statistical differences between treatments were evaluated using the analysis of variance (ANOVA) followed by Fisher’s least significant difference (LSD) test (p < 0.05). Traditional smoking resulted in greater dehydration, with moisture content reduced by approximately 8–15% and water activity lower by about 0.04–0.09 compared with industrial smoking. Traditionally smoked products also showed higher mass loss (up to 10–12%) and lower L* values, indicating darker color. Texture profile analysis indicated higher hardness values in several traditionally smoked products, particularly in sausages and pancetta. In contrast, industrial smoking resulted in higher moisture retention and more uniform physicochemical characteristics. The differences between smoking regimes were less pronounced in dry-cured pork neck. These results demonstrate that smoking technology significantly influences dehydration dynamics and several technological quality parameters of cured meat products, providing useful information for optimizing smoking regimes in traditional and industrial meat processing. Full article
(This article belongs to the Section Food Process Engineering)
23 pages, 6469 KB  
Article
Integrated CFD Modeling of Combustion, Heat Transfer, and Oxide Scale Growth in Steel Slab Reheating
by Mario Ulises Calderón Rojas, Constantin Alberto Hernández Bocanegra, José Ángel Ramos Banderas, Nancy Margarita López Granados, Nicolás David Herrera Sandoval and Juan Carlos Hernández Bocanegra
Processes 2026, 14(6), 1011; https://doi.org/10.3390/pr14061011 - 21 Mar 2026
Viewed by 544
Abstract
In this study, a three-dimensional simulation of a walking-beam reheating furnace was developed to improve the steel slab reheating process and reduce surface oxidation kinetics using computational fluid dynamics (CFD). Combustion, heat transfer, fluid dynamics, and chemical reaction models were integrated into the [...] Read more.
In this study, a three-dimensional simulation of a walking-beam reheating furnace was developed to improve the steel slab reheating process and reduce surface oxidation kinetics using computational fluid dynamics (CFD). Combustion, heat transfer, fluid dynamics, and chemical reaction models were integrated into the numerical framework of this study. In addition, dynamic mesh remeshing was coupled through user-defined functions (UDFs), enabling the simultaneous simulation of slab movement and evolution of the involved transport phenomena. Turbulence was modeled with the realizable k-ε formulation, combustion with the Eddy Dissipation model, and radiation with the P-1 model coupled with WSGGM to include CO2 and H2O gas radiation. Scale formation was modeled using customized functions based on Arrhenius-type kinetics and Wagner’s oxidation model, evaluating its growth as a function of time, temperature, and furnace atmosphere. The predicted thermal evolution inside the furnace was validated using industrial data, yielding an average deviation of 5%. Furthermore, the proposed operating conditions led to an average slab temperature of 1289.77 °C at the exit of the homogenization zone, which was 16 °C higher than that under the current operation but still within the target range (1250 ± 50 °C). The reduction in combustion air decreased energy losses and improved product quality, lowering the molar oxygen content in the furnace atmosphere from 4.9 × 102 mol to 6.7 × 101 mol. Additionally, annual savings of 4,793,472 kg of natural gas and 13,884 tons of steel were estimated owing to reduced oxidation losses. The proposed air–fuel adjustment led to estimated annual energy savings (equivalent to 4,793,472 kg of natural gas) and a reduction in material loss due to oxidation from 4.5% to 3.75% (an absolute reduction of 0.75 percentage points; relative reduction ≈ 16.7%), which has a significant industrial impact on metal conservation and descaling cost reduction. Although there are CFD studies on plate overheating and scale growth separately, this work presents three main contributions: (1) the integration, within a single numerical framework, of combustion, radiation, species transport, oxidation kinetics, and actual plate movement using a dynamic mesh; (2) validation against continuous industrial records (16 thermocouples) and quantification of operational benefits such as fuel savings and reduced material loss; and (3) a comparative analysis between actual and optimized conditions, which standardize the air–methane ratio. Full article
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20 pages, 2702 KB  
Article
Mathematical Modeling of Microbial Hydrocarbon Degradation Using Analytical and Runge–Kutta Methods
by Cristian Mugurel Iorga, Gabriel Murariu and Lucian Georgescu
Processes 2026, 14(6), 973; https://doi.org/10.3390/pr14060973 - 18 Mar 2026
Viewed by 486
Abstract
Petroleum hydrocarbons remain major environmental contaminants, and understanding the mechanisms governing their biodegradation is essential for designing effective remediation plans. The strategy in this article is slightly different from other cases in the literature. Such literature models require, for their elaboration, a significant [...] Read more.
Petroleum hydrocarbons remain major environmental contaminants, and understanding the mechanisms governing their biodegradation is essential for designing effective remediation plans. The strategy in this article is slightly different from other cases in the literature. Such literature models require, for their elaboration, a significant number of experiments; the number of experimental determinations is at least proportional to the square of the number of constants introduced in the mathematical expressions. For this reason, the strategy followed in this article is different—starting from a set of experiments carried out and presented in a coherent and published manner, a simple methodology for building specific and minimal models, which will allow solving specific problems, was effectively developed. This study develops a nonlinear mathematical structure, expressed as a system of coupled differential equations, that simultaneously describes the degradation of petroleum hydrocarbons and the dynamics of hydrocarbon-degrading bacteria and fungi in soil–sludge mixtures. The model was calibrated using experimental data obtained from biopiles prepared with different volumetric ratios of contaminated soil and sewage sludge. Approximate analytical solutions were derived and the distributed constants were evaluated. For a consistent discussion, the analytical solutions were assessed against numerical desk simulations performed with a classical fourth-order Runge–Kutta method, which accurately reproduced the nonlinear behavior of the specific system. This numerical approach was chosen in order to overcome the proper difficulties encountered in this strategy implementation. The results show that the soil–sludge ratio strongly influences biodegradation efficiency, while kinetic parameters determine whether microbial communities evolve toward a stationary regime or accelerated contaminant removal. The combined analytical–numerical framework provides a robust predictive tool for optimizing mixture composition and improving the design of bioremediation treatments for petroleum-contaminated soils. Full article
(This article belongs to the Special Issue Innovations in Solid Waste Treatment and Resource Utilization)
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12 pages, 563 KB  
Article
A Three-Phase Electromagnetic Harvester with a Single-Spring Coupled Moving Magnet Assembly
by Marcin Fronc, Grzegorz Litak, Krzysztof Kolano, Magdalena Przybylska-Fronc and Mateusz Waśkowicz
Processes 2026, 14(6), 966; https://doi.org/10.3390/pr14060966 - 18 Mar 2026
Viewed by 358
Abstract
Vibration energy harvesting is a promising approach to support and supplement power, thereby extending the lifetime of low-power sensor nodes under suitable vibration conditions, i.e., in environments where sufficient ambient vibrations are available. It is not a universal autonomous power-supply solution, particularly when [...] Read more.
Vibration energy harvesting is a promising approach to support and supplement power, thereby extending the lifetime of low-power sensor nodes under suitable vibration conditions, i.e., in environments where sufficient ambient vibrations are available. It is not a universal autonomous power-supply solution, particularly when generalized across the Internet of Things (IoT), because the harvested power is typically limited to the µW–mW range and depends strongly on the vibration frequency content, amplitude, and operating point relative to resonance. Furthermore, many practical harvesters rely on resonant mechanisms, which are inherently narrowband, and therefore their performance can degrade significantly under detuning or broadband/variable-frequency excitations. In addition, energy-management and power-conditioning electronics (rectification, storage, and regulation) are required to convert the generated electrical energy into a stable and usable DC supply for practical loads. In this work, we develop a nonlinear state-space model of a three-phase electromagnetic vibration energy harvester with spatially displaced coils and evaluate its electrical output characteristics and DC power behavior using numerical simulations. Full article
(This article belongs to the Special Issue Advances in the Control of Complex Dynamic Systems)
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12 pages, 2930 KB  
Article
Design of Carbon Nanocomposites Based on PLA and PCL—From Microscratch Testing to Self-Healing Behavior
by Todor Batakliev, Evgeni Ivanov, Vladimir Georgiev, Verislav Angelov and Rumiana Kotsilkova
Processes 2026, 14(6), 956; https://doi.org/10.3390/pr14060956 - 17 Mar 2026
Viewed by 493
Abstract
Biodegradable nanocomposite materials possessing self-healing behavior are emerging as an attractive option of being used in advanced mechatronic systems. The current study is focused on a thorough examination of the micromechanical properties of graphene–reinforced polylactic acid (PLA)/polycaprolactone (PCL) composite samples, followed by estimation [...] Read more.
Biodegradable nanocomposite materials possessing self-healing behavior are emerging as an attractive option of being used in advanced mechatronic systems. The current study is focused on a thorough examination of the micromechanical properties of graphene–reinforced polylactic acid (PLA)/polycaprolactone (PCL) composite samples, followed by estimation of their self-healing behavior upon heating. Polymer blend–based nanocomposite materials were prepared using the green and reliable in terms of good nanofiller dispersion melt extrusion method. 3D printed nanocomposite specimens with impeccable flatness were subjected to fine microscratch testing by applying a constant force experimental mode. The surface resistance of the three-component polymer materials against the lateral movement of the stylus fulfilling the scratch and the impact of the dual-phase PLA/PCL ratio on the nanocomposite mechanical performance were estimated by calculation of the coefficient of friction (COF = Fx/Fz). COF values in the range of 0.8–1.4 indicated excellent nanocomposite resilience against scratch. Creating a heterogeneous polymer system that combines phase-separated soft and hard domains with close melt and glass transition temperatures, respectively, may facilitate the physical flow of macromolecular chains into voids or free volume areas. This aspect can be critical in the achievement of thermally–induced self-healing properties of the composite material. Scanning electron microscopy (SEM) imaging of the microscratches, made before and after Joule heating of the polymer samples, revealed a significant degree of surface recovery and a sensible reduction in the width of the adjusted scratch grooves. Full article
(This article belongs to the Special Issue Synthesis and Applications of Nanomaterials)
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20 pages, 1929 KB  
Article
Upcycling of Date Fruit By-Products from Bioethanol Production: Structural Characterization of Polysaccharides and Phenolic Compounds
by Mohamad Khatib, Lorenzo Cecchi, Margherita Campo, Pamela Vignolini, Chiara Cassiani, Paolo Fiume and Nadia Mulinacci
Processes 2026, 14(6), 948; https://doi.org/10.3390/pr14060948 - 16 Mar 2026
Viewed by 466
Abstract
Date palm (Phoenix dactylifera L.) by-products from bioethanol production represent an underutilized resource rich in bioactive molecules. This study aims to their valorization through characterization of polysaccharides and phenolic compounds from the Medjool variety, both before and after yeast fermentation for bioethanol [...] Read more.
Date palm (Phoenix dactylifera L.) by-products from bioethanol production represent an underutilized resource rich in bioactive molecules. This study aims to their valorization through characterization of polysaccharides and phenolic compounds from the Medjool variety, both before and after yeast fermentation for bioethanol production. Three sequential types of by-products were analyzed—Ext1 (post hot-extraction), Ext2 (post fermentation), and Ext3 (post distillation)—and compared with Dat-Me. High Performance Liquid Chromatograp-Diode Array Detector-Mass Spectrometry (HPLC-DAD-MS) analysis allowed identifying 22 phenolic compounds, primarily cinnamic acid derivatives and glycosylated flavones such as luteolin and chrysoeriol. Fermentation increased total phenolic content from dry weight, while leading to an improved polysaccharide recovery (i.e., from 14.2% to 42.1% dry weight). Two polysaccharide fractions (F1 and F2) were isolated and characterized by 1H-NMR and Dynamic Light Scattering (DLS). F1 is a pectic polysaccharide, with a galacturonic acid content ranging from 24.2% (Ext3) to 52.2% (Dat-Me), a degree of methylation (DM) between 34.4 and 50.6%, and a degree of acetylation (DA) of 23.6–42.2%. F2 consists of a non-pectic polysaccharide, characterized by a low galacturonic acid content (5.6–6.8%) and a DM of 12.6–47.1%, but it is highly acetylated, with a DA ranging from 90.1 to 93.3%. DLS analysis confirmed fermentation-induced depolymerization, with molecular weights ranging from 6.6 × 104 to 8.5 × 105 KDa for both the fractions. Overall, Medjool date by-products obtained after bioethanol production represent a sustainable source of high-value phenolic antioxidants and polysaccharides with different structures suitable for future applications in food, pharmaceutical, and cosmetic formulations. Full article
(This article belongs to the Special Issue Biofuels Production Processes)
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25 pages, 858 KB  
Article
Structural, Physicochemical, and Sensory Implications of Progressive Sodium Reduction with Nutritional Yeast in Cooked Sausages
by Ivica Kos, Ivana Džepina, Jelka Pleadin, Nina Kudumija, Ante Rako, Marina Ravlić, Darija Bendelja Ljoljić and Ivan Vnučec
Processes 2026, 14(6), 904; https://doi.org/10.3390/pr14060904 - 12 Mar 2026
Viewed by 485
Abstract
Excessive sodium intake is a public health concern, although sodium chloride is technologically essential in comminuted meat systems due to its role in protein solubilization, water binding, and gel formation. This study evaluated the extent to which progressive sodium reduction combined with nutritional [...] Read more.
Excessive sodium intake is a public health concern, although sodium chloride is technologically essential in comminuted meat systems due to its role in protein solubilization, water binding, and gel formation. This study evaluated the extent to which progressive sodium reduction combined with nutritional yeast supplementation preserves physicochemical stability, structural integrity, and sensory quality in cooked sausages. Four formulations were produced: a referent and three reduced-salt (NaCl) treatments (−15%, −25%, −35%) containing 2% nutritional yeast (1% in the referent). Water activity increased significantly with salt reduction (0.969–0.977; p < 0.05), accompanied by higher lightness (CIE L*) and yellowness (CIE b*), whereas instrumental redness (CIE a*) remained stable. Proximate composition was unaffected except for the expected decrease in ash and salt content (p < 0.05), while free glutamic acid increased significantly in reduced-salt treatments (0.67 vs. 0.87–0.91 g/kg; p < 0.05). Instrumental texture parameters indicated preserved cutting resistance, although repeated compression revealed reduced structural resilience at the 35% reduction level. Sensory evaluation showed that reductions up to 25% maintained overall typicality and balance, whereas 35% reduction decreased saltiness, slice coherence, aroma harmony, and texture typicality (p < 0.05). Principal component analysis confirmed a multivariate shift from a salt-stabilized structural domain to a softer, yeast-associated sensory domain at the highest reduction level. Moderate sodium reduction combined with nutritional yeast is therefore technologically and sensorially feasible in this product category. Full article
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12 pages, 248 KB  
Article
Nutritional Composition, Phenolic Compounds, and Antioxidant Capacity of Blue Corn Tortillas Fortified with Quelites (Amaranthus hybridus L.)
by Alma Haydee Astorga-Gaxiola, Manuel Adrian Picos-Salas, Luis Angel Cabanillas-Bojórquez, Nayely Leyva-López, Erick Paul Gutiérrez-Grijalva, Melissa García-Carrasco, J. Basilio Heredia and Jesús Estrada-Manjarrez
Processes 2026, 14(5), 874; https://doi.org/10.3390/pr14050874 - 9 Mar 2026
Viewed by 573
Abstract
Tortillas are an essential food staple in the Mexican diet due to their nutritional value. Blue corn tortillas have been reported as a source of bioactive compounds, such as phenolic compounds and flavonoids. Likewise, the blue corn tortillas have been studied to enhance [...] Read more.
Tortillas are an essential food staple in the Mexican diet due to their nutritional value. Blue corn tortillas have been reported as a source of bioactive compounds, such as phenolic compounds and flavonoids. Likewise, the blue corn tortillas have been studied to enhance the nutritional and nutraceutical composition. In this sense, Quelites are a large family of plants with macronutrient and micronutrient content, as well as a source of phenolic compounds, flavonoids, and carotenoids. Among these, Amaranthus hybridus L. could fortify the blue corn tortilla composition. Therefore, this study aims to fortify blue corn tortillas with different concentrations of Quelites flours. The total flavonoid and phenolic compounds content, as well as the antioxidant capacity and identification of phenolic compounds, were evaluated on tortillas fortified with Quelites. The addition of Quelites to blue corn tortillas reduced the lipid and protein content, carbohydrate, and flavonoid content, and enhance the antioxidant capacity of tortillas as measured by FRAP, ORAC, and TEAC assays. Also, caffeic acid, chlorogenic acid, ferulic acid, and sinapic acid were identified on blue corn tortillas fortified with Quelites. These results support the use of A. hybridus L. as an ingredient to improve the nutrient and nutraceutical composition of foods. Full article
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21 pages, 2520 KB  
Article
Combined Effect of Environmental pH and Pulsed Electric Fields on Bacillus Coagulans Vegetative Cells Inactivation
by Varvara Andreou, Ioannis Stavrakakis, Marianna Giannoglou, Petros Taoukis and George Katsaros
Processes 2026, 14(5), 856; https://doi.org/10.3390/pr14050856 - 7 Mar 2026
Viewed by 510
Abstract
The aim of this study was to model the inactivation of Bacillus coagulans vegetative cells subjected to thermal processing (60–90 °C, 1–30 min) and pulsed electric fields (PEF) (11, 15, and 20 kV/cm, up to 0.12 s, 20 Hz, 15 μs pulse width) [...] Read more.
The aim of this study was to model the inactivation of Bacillus coagulans vegetative cells subjected to thermal processing (60–90 °C, 1–30 min) and pulsed electric fields (PEF) (11, 15, and 20 kV/cm, up to 0.12 s, 20 Hz, 15 μs pulse width) at different pH environments (4.0 to 7.0) and in real food matrices (peach puree and carrot juice). Microbial survival data were successfully described using the Gompertz model. Thermal experiments confirmed the high heat resistance of B. coagulans, with maximum survival observed at pH 5.0–6.0. PEF treatments were effective in inactivating vegetative cells, with more intense PEF conditions leading to faster inactivation. Complete inactivation was achieved in less than 15 ms at low pH (4.5), while more than 120 ms was required at pH 6.0. Preheating samples to 50–60 °C prior to PEF significantly reduced the PEF processing time needed for full inactivation, by approximately 88%. In food matrices, the inactivation rate in peach puree was twice as high as in carrot juice, but up to 8 times lower than in buffer solutions. Cells were inactivated twice as fast in peach puree as in carrot juice. This study provides quantitative technical parameter references for optimizing non-thermal processing technologies for acidic/weakly acidic fruit and vegetable products. Full article
(This article belongs to the Section Food Process Engineering)
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18 pages, 3120 KB  
Article
Use of Demerara and VHP Sugars Combined with Various Nitrogen Sources for Enhanced Fructosyltransferase Production in Aspergillus oryzae IPT-301
by Amanda P. S. Cavini, Mariana F. M. Cardoso, Ana Carolina Vieira, Marta Filipa Simões, Alex Fernando de Almeida, Maria L. A. N. Teixeira, Sergio A. V. Morales, Alfredo E. Maiorano, Rafael F. Perna and Cristiane A. Ottoni
Processes 2026, 14(5), 840; https://doi.org/10.3390/pr14050840 - 5 Mar 2026
Viewed by 497
Abstract
This study investigated the effect of low-cost carbon and nitrogen sources on fructosyltransferase (FTase) production by Aspergillus oryzae IPT-301, aiming to optimize the enzymatic synthesis of fructooligosaccharides (FOS), prebiotic compounds valued for their bifidogenic effects. FTase is a key enzyme in transfructosylation, the [...] Read more.
This study investigated the effect of low-cost carbon and nitrogen sources on fructosyltransferase (FTase) production by Aspergillus oryzae IPT-301, aiming to optimize the enzymatic synthesis of fructooligosaccharides (FOS), prebiotic compounds valued for their bifidogenic effects. FTase is a key enzyme in transfructosylation, the central step in FOS production. To reduce production costs, Very High Polarization (VHP) and Demerara (DM) sugars were evaluated as carbon sources, while sodium nitrate (NaNO3), ammonium sulfate (NH4)2SO4, and urea were tested as nitrogen sources. FTase production, both extracellular and intracellular, was conducted under submerged fermentation at 30 °C and 200 rpm for 72 h. DM sugar outperformed VHP, increasing extracellular and intracellular transfructosylation activity (AT) by 2.3-fold and 2.1-fold, respectively. Among nitrogen sources, NaNO3 was most effective in DM-containing media, yielding 1.6–2.0 times higher extracellular AT and up to 4.7 times greater intracellular activity compared to other nitrogen sources. These findings suggest that the combination of DM sugar and NaNO3 significantly enhances FTase yield, providing a cost-effective strategy for industrial-scale FOS production. Full article
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16 pages, 1553 KB  
Article
Machine-Learning Algorithm and Decline-Curve Analysis Comparison in Forecasting Gas Production
by Dan-Romulus Jacota, Cristina Roxana Popa, Maria Tănase and Cristina Veres
Processes 2026, 14(5), 826; https://doi.org/10.3390/pr14050826 - 3 Mar 2026
Viewed by 679
Abstract
This study utilizes machine-learning algorithms to reinterpret existing datasets originally plotted using Decline-Curve Analysis (DCA), aiming to enhance predictive accuracy without requiring new field-data acquisition. Historical production records were compiled: monthly oil/gas rates, bottom-hole pressures, and cumulative productions, which were fitted to Arps [...] Read more.
This study utilizes machine-learning algorithms to reinterpret existing datasets originally plotted using Decline-Curve Analysis (DCA), aiming to enhance predictive accuracy without requiring new field-data acquisition. Historical production records were compiled: monthly oil/gas rates, bottom-hole pressures, and cumulative productions, which were fitted to Arps equations via least-squares optimization, and key decline parameters, such as initial rate, nominal decline rate, and hyperbolic exponent, served as input data. Four machine-learning models were trained and validated: Artificial Neural Networks (ANN), Support Vector Machines (SVM), and Linear Regression (LR), using 80/20 train–test splits and 5-fold cross-validation. Models were evaluated using Mean Squared Error (MSE), Root Mean Square Error (RMSE), Mean Absolute Error (MAE), and coefficient of determination (R2). The ANN emerged as the best-performing method, achieving near-unity predictive accuracy (R2 ≈ 1) on the independent test set, with low error values (MSE = 0.0012 Ncm2/month2, RMSE = 0.035 Ncm/month, MAE = 0.028 Ncm/month) for oil production rates. Similar levels of accuracy were obtained for gas rates and pressures. These results reflect the strong and highly regular relationships present in the dataset analyzed rather than an exact zero-error fit. The multi-layer architecture of the ANN effectively captured the nonlinear interactions between Arps parameters and transient flow regimes, outperforming the empirical and physics-constrained approaches. Linear regression yielded strong results (R2 = 0.98, RMSE = 0.15 Ncm/month) but faltered in high-decline scenarios, failing to model exponential tails accurately. SVM exhibited the highest deviations (RMSE = 0.42 Ncm/month, R2 = 0.89), attributable to kernel sensitivity in sparse, noisy decline data. RF provided intermediate performance (R2 = 0.97). This ANN-driven approach redefines decline analysis by automating parameter tuning and uncertainty quantification, reducing forecasting errors by 85% versus classical Arps methods. Full article
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23 pages, 4186 KB  
Article
Chemical Titrations and Temperature-Programmed Desorption Study of the Surface Chemistry of Graphene Oxide and 12-Tungstophosphoric Acid Nanocomposite
by Milica Milanković, Željko Mravik, Bojana Nedić Vasiljević, Danica Bajuk-Bogdanović, Snežana Uskoković-Marković and Zoran Jovanović
Processes 2026, 14(5), 825; https://doi.org/10.3390/pr14050825 - 3 Mar 2026
Cited by 2 | Viewed by 634
Abstract
The surface chemistry of graphene oxide (GO) and its nanocomposite with 12-tungstophosphoric acid (WPA) (up to 50 wt.% WPA) was studied both in aqueous suspension and in the solid state. The titrations revealed the formation of the composite already in the suspension and [...] Read more.
The surface chemistry of graphene oxide (GO) and its nanocomposite with 12-tungstophosphoric acid (WPA) (up to 50 wt.% WPA) was studied both in aqueous suspension and in the solid state. The titrations revealed the formation of the composite already in the suspension and that WPA influences GO’s functionalities and their conversion (-COOR to -COOH). There is a loading of WPA (>20 wt.%) beyond which the WPA dominates the chemical character of the GO/WPA suspension. Part of the nanocomposite titrated with NaOH was processed into a powdered form and compared with an annealed sample (450 °C, Ar atmosphere). An FTIR analysis revealed the removal of functional groups in both titrated and thermally annealed samples. Annealing did not induce structural changes in WPA within the composite, whereas titration led to noticeable modifications of WPA-related bands. The TPD measurements revealed that the extent of functional group removal by titration was lower compared to annealing. The zeta-potential measurements demonstrated improved stability of the nanocomposite as the WPA content increased. Methylene blue adsorption experiments showed that the presence of oxygen functional groups and WPA on the GO enhances adsorption performance compared to pristine GO. Titration improved the adsorption capacity of the composites, whereas annealing completely suppressed their adsorption properties. Full article
(This article belongs to the Special Issue Graphene Oxide: From Synthesis to Applications)
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21 pages, 3979 KB  
Article
A Docker-Enabled Real-Time Framework for Robotic Applications in Heterogeneous ROS 2 Environments
by Ji Min Lim, Keon Woo Kim, Byoung Wook Choi and Raimarius Delgado
Processes 2026, 14(5), 804; https://doi.org/10.3390/pr14050804 - 28 Feb 2026
Viewed by 994
Abstract
Real-time performance remains a core requirement for safety-critical robotic applications. ROS 2 has become a de facto middleware standard, while Docker is increasingly adopted for modular and portable deployment. However, embedded hardware updates often constrain Linux distributions and real-time kernel versions, while existing [...] Read more.
Real-time performance remains a core requirement for safety-critical robotic applications. ROS 2 has become a de facto middleware standard, while Docker is increasingly adopted for modular and portable deployment. However, embedded hardware updates often constrain Linux distributions and real-time kernel versions, while existing software stacks depend on older ROS 2 releases and legacy libraries. This mismatch forces costly porting and revalidation, motivating heterogeneous deployments that mix ROS 2 versions across host and Docker container runtimes. Yet the overheads introduced by Docker and cross-version ROS 2 communication are not well quantified in terms of real-time guarantees. This paper presents a Docker-enabled real-time framework for evaluating robotic applications in heterogeneous ROS 2 deployments. The framework integrates an RT-PREEMPT–patched Linux kernel, Dockerized ROS 2 distributions, and configurable cross-version communication pathways to enable controlled, repeatable experiments without full-stack migration. We empirically quantify Docker-induced effects on real-time execution using task periodicity, jitter, and response time, and assess ROS 2 communication using end-to-end latency under host-only, container-only, and hybrid configurations. To demonstrate practical viability, we apply the framework to an operational mobile-robot use case that integrates legacy control code with new modules, including a reinforcement-learning decision layer, within a mixed host–container ROS 2 stack. The resulting analyses provide reusable tooling and actionable guidelines for deploying deterministic ROS 2 systems under containerized heterogeneous constraints. Full article
(This article belongs to the Special Issue Advances in the Control of Complex Dynamic Systems)
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35 pages, 1340 KB  
Article
Behind Macrophage Polarization in Wound Healing: A Mathematical Quest
by Prateek Gupta and Doraiswami Ramkrishna
Processes 2026, 14(5), 790; https://doi.org/10.3390/pr14050790 - 28 Feb 2026
Viewed by 549
Abstract
Cellular heterogeneity in immune responses helps us fight diverse pathogenic threats. Here, we present a resource-constrained, optimization-based flux-allocation paradigm by which phenotypic heterogeneity emerges in macrophage polarization. We build a six-dimensional mechanistic model of arginine metabolism and study how constrained resource allocation shapes [...] Read more.
Cellular heterogeneity in immune responses helps us fight diverse pathogenic threats. Here, we present a resource-constrained, optimization-based flux-allocation paradigm by which phenotypic heterogeneity emerges in macrophage polarization. We build a six-dimensional mechanistic model of arginine metabolism and study how constrained resource allocation shapes polarization and population heterogeneity. In a baseline formulation without explicit resource budgets, the system is effectively monostable under fixed cytokine inputs, and heterogeneous populations collapse onto a single polarization trajectory, consistent with well-resolving wounds. Introducing cybernetic variables that actively distribute finite resources between competing metabolic alternatives enables ultrasensitive resource partitioning that amplifies feedback and produces robust bistability under fixed cytokine cues. Embedding this intracellular model in a structured population balance framework, we show that in the advection-dominated regime, an initial macrophage cloud splits along two cybernetic equilibria, yielding approximately symmetric M1-like (iNOShigh/Arg1low) and M2-like (Arg1high/iNOSlow) peaks. Adding small isotropic diffusion in trait space, its coupling to NO-dependent apoptosis skews mass toward the Arg1high/iNOSlow branch, producing persistent asymmetric bimodality with a denser M2-like subpopulation. The model matches reported dynamics of iNOS expression, including gradual convergence of iNOSlow and iNOShigh subpopulations under ±IFNγ treatment. Such models can accelerate discovery of therapies for chronic wounds by predicting population-level responses to treatment. Full article
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23 pages, 1670 KB  
Article
Isolation of Biopolymer Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) via Aqueous Two-Phase Systems (ATPS): Towards Optimisation of Green Purification Procedures
by Guillermo Martínez, Gabriela Guillena and Rosa María Martínez-Espinosa
Processes 2026, 14(5), 764; https://doi.org/10.3390/pr14050764 - 26 Feb 2026
Viewed by 505
Abstract
The development of bioplastics, such as poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), as sustainable alternatives to petroleum-based plastics, requires efforts to reduce their economic and environmental impacts. Aqueous Two-Phase System (ATPS) represents a sustainable alternative to isolate PHBV, as it is water-based. A polyethylene glycol (PEG8000)/phosphate salts-based [...] Read more.
The development of bioplastics, such as poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV), as sustainable alternatives to petroleum-based plastics, requires efforts to reduce their economic and environmental impacts. Aqueous Two-Phase System (ATPS) represents a sustainable alternative to isolate PHBV, as it is water-based. A polyethylene glycol (PEG8000)/phosphate salts-based ATPS was employed as a sustainable approach to isolate and purify PHBV produced by the haloarchaeon Haloferax mediterranei. The Taguchi design method was used to optimise an ATPS, integrating variables such as the concentration of commercial PEG8000 and phosphate salts, extraction temperature, system pH, and biomass-to-system volume ratio. Results revealed a maximum PHBV recovery of 80% with a purity of 93% under the following conditions: 20% of PEG8000, 20% of phosphate salts, pH of 7, 50 °C, and a 1:100 ratio. Furthermore, the potential recycling of ATPS components was studied to reduce the overall cost of the biopolymer isolation procedure. However, a significant decrease in the PHBV recovery was observed (52% when using recycled components). Finally, the use of PEG8000 from ethylene glycol (EG) polymerisation, aimed at the valorisation of EG obtained from other industrial processes, yielded comparable recovery and purity of PHBV (78% and 89%, respectively). Full article
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21 pages, 4286 KB  
Article
Synthesis of Carbon Nanotubes on Active Silica for Enhanced Cementitious Mortars
by Alaíde Marta dos Santos, Cláudio Ernani Martins Oliveira, Viviany Geraldo, Jaqueline do Carmo Lima Carvalho and Wanna Carvalho Fontes
Processes 2026, 14(4), 676; https://doi.org/10.3390/pr14040676 - 16 Feb 2026
Viewed by 545
Abstract
The incorporation of carbon nanotubes (CNT) into cementitious composites has shown strong potential for enhancing mechanical performance. However, conventional dispersion methods, such as ultrasonication and chemical functionalization, are costly, complex, and difficult to scale for construction applications. This study introduces an alternative approach [...] Read more.
The incorporation of carbon nanotubes (CNT) into cementitious composites has shown strong potential for enhancing mechanical performance. However, conventional dispersion methods, such as ultrasonication and chemical functionalization, are costly, complex, and difficult to scale for construction applications. This study introduces an alternative approach based on the in situ synthesis of CNT on active silica grains, which enables their direct incorporation into mortar formulations. The material was produced via chemical vapor deposition and characterized by scanning electron microscopy, thermogravimetric analysis, energy-dispersive spectroscopy, and Fourier-transform infrared spectroscopy. The resulting nanostructured active silica (NAS) exhibited high carbon content (80.7%) and a 1350% yield, confirming efficient nanotubular deposition. Residual oxygen (9.12%), Mg (0.75%), and Al (0.17%) indicated partial retention of catalytic species, while Fe–Co promoters with Mg–Al modifiers enabled a catalytically active surface favorable to CNT growth. Mortars incorporating NAS restored the flexural strength losses associated with cement replacement by silica, achieving values comparable to the reference mixture and outperforming the silica-only sample; compressive strength increased by ~16.5%. These results demonstrate that NAS promotes effective CNT dispersion at the composite scale without additional dispersion techniques, reduces process complexity, and adds value to commercial silica, providing a scalable route for developing nanostructured cementitious composites for construction applications. Full article
(This article belongs to the Special Issue Production, Purification and Applications of Carbon Nanomaterials)
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28 pages, 2227 KB  
Article
Development and Quality Characteristics of Grilled Pacific Cod (Gadus macrocephalus) Fillet Home Meal Replacement (HMR)
by Mi-Jeong Lee, Ah Hyun Son, Khawaja Muhammad Imran Bashir, Hye-Ryeon An, Dong-Myeong Kang, Sana Mansoor, Jae-Suk Choi and Jae Hak Sohn
Processes 2026, 14(4), 669; https://doi.org/10.3390/pr14040669 - 15 Feb 2026
Viewed by 823
Abstract
Changes in lifestyle and food consumption patterns have contributed to a growing demand for home meal replacements (HMRs), emphasizing the need for high-quality seafood-based products. This study aimed to develop a grilled Pacific cod (Gadus macrocephalus) fillet HMR prototype and to [...] Read more.
Changes in lifestyle and food consumption patterns have contributed to a growing demand for home meal replacements (HMRs), emphasizing the need for high-quality seafood-based products. This study aimed to develop a grilled Pacific cod (Gadus macrocephalus) fillet HMR prototype and to evaluate optimal processing conditions, quality characteristics, and shelf-life stability. High-frequency thawing was selected to improve raw material handling by minimizing drip loss to 11.91% and reducing thawing time to 15 min. A thyme-based marinade at a concentration of 3% for 20 min was applied to reduce odor and enhance sensory quality, and superheated steam grilling was compared with conventional heating methods. Processing parameters were optimized using response surface methodology, and smoking conditions were evaluated using different wood types. Superheated steam grilling produced superior sensory attributes under optimal conditions of 340 °C for 4 min, followed by cherry wood smoking at 60 °C for 5 min. The combined processing approach reduced total bacterial counts while maintaining acceptable physicochemical quality characteristics. Thermal processing increased texture firmness and nutritional density due to moisture loss, reduced lipid oxidation, and modified amino acid and fatty acid profiles. Shelf-life modeling indicated safe storage for up to 18 months under frozen conditions. These findings demonstrate that integrated marination, superheated steam grilling, and controlled smoking can be effectively applied to produce a safe, stable, and high-quality grilled Pacific cod HMR product. Full article
(This article belongs to the Special Issue Food Biochemistry and Health: Recent Developments and Perspectives)
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15 pages, 1789 KB  
Article
The Factors That Influence the Intensity of the Stress Shadow Impact on Gas Recovery from the Marcellus Shale
by Mohamed El Sgher, Kashy Aminian and Samuel Ameri
Processes 2026, 14(4), 614; https://doi.org/10.3390/pr14040614 - 10 Feb 2026
Viewed by 381
Abstract
Economic gas recovery from shale reservoirs is inherently difficult because of the extremely low permeability of these formations. To overcome this challenge, horizontal wells are drilled and subjected to multi-stage hydraulic fracturing treatments, which generate high-conductivity flow pathways. The adoption of these technologies [...] Read more.
Economic gas recovery from shale reservoirs is inherently difficult because of the extremely low permeability of these formations. To overcome this challenge, horizontal wells are drilled and subjected to multi-stage hydraulic fracturing treatments, which generate high-conductivity flow pathways. The adoption of these technologies has significantly boosted the economic recovery of gas from shale formations, particularly the Marcellus Shale, which stands as the most productive shale gas play in the United States. The effectiveness of a fracturing treatment in enabling economic gas production from shale reservoirs is governed by the characteristics of the fractures it creates. The propagation of initial fracture, during multi-stage hydraulic fracturing, modifies the initial stress conditions in the surrounding area, commonly referred to as a “stress shadow.” The stress shadow restricts the initiation and subsequent propagation of later fracture stages, leading to the development of less favorable fracture properties. As a result, the uneven contribution of individual fracture stages to gas flow ultimately diminishes overall gas recovery from the horizontal well. For efficient gas drainage from the shale, the fracture stages are often closely spaced. When fracture stages are placed in close proximity, the stress shadow effect can be intensified. Thus, accounting for the stress shadow is essential in the design of hydraulic fracture treatments. This study investigates how fracture spacing, injected fluid volume, and fluid type influence the magnitude of the stress shadow effect, its impact on fracture properties, and the resulting gas recovery from the Marcellus Shale. The goal is to facilitate the optimization of the hydraulic fracture design to mitigate the stress shadow impact and enhance gas production. Data from several Marcellus Shale horizontal wells, along with published findings, were compiled and analyzed to determine the petrophysical and geomechanical characteristics of the formation. These results were then used to construct a reservoir model representative of a Marcellus Shale horizontal well. Fracture properties, altered by the stress shadow, were assessed through hydraulic fracturing simulations and incorporated into the model. Ultimately, the reservoir model was employed to predict the production performance. The results of the investigation confirmed that close stage spacing intensifies the impact of the stress shadow. The stress shadow was found to impair fracture conductivity which negatively impacted gas recovery. The negative impact of the stress shadow on gas recovery was observed to gradually diminish as the production rate declined over time. The volume and type of the fluid injected during fracturing treatment can amplify the stress shadow’s impact. Full article
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21 pages, 4018 KB  
Article
Guided Pairwise Variable Optimization Method Applied to an Alpha-Type Stirling Engine
by S. Islas-Pereda, N. Velázquez-Limón, Ricardo Beltran-Chacon, J. A. Aguilar-Jiménez and R. López-Zavala
Processes 2026, 14(4), 620; https://doi.org/10.3390/pr14040620 - 10 Feb 2026
Viewed by 601
Abstract
This study presents a guided pairwise variable optimization methodology applied to an Alpha-type Stirling engine to enhance its efficiency by optimizing its design parameters. The study was conducted using a second-order numerical model implemented in the MATLAB platform (R2019a). The proposed methodology, referred [...] Read more.
This study presents a guided pairwise variable optimization methodology applied to an Alpha-type Stirling engine to enhance its efficiency by optimizing its design parameters. The study was conducted using a second-order numerical model implemented in the MATLAB platform (R2019a). The proposed methodology, referred to as Guided Pairwise Variable Optimization (G.I.P.O.), is based on the identification, categorization, and prioritization of interactions between pairs of variables, establishing guidelines for conducting parametric explorations that allow the proper selection of the design dimensions of the Stirling engine variables. The piston stroke, cylinder diameter, piston crown length, phase angle between cylinders, regenerator length and diameter, and the length and diameter of the heater and cooler tubes were analyzed. This methodology resulted in a 4.55% increase in efficiency compared to univariate optimization techniques, demonstrating its effectiveness in reducing computational complexity while improving system performance. Full article
(This article belongs to the Special Issue Numerical Modeling and Optimization of Fluid Flow in Engines)
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21 pages, 3171 KB  
Article
Automated Fiber Placement Gap Width Prediction Using a Transformer-Based Deep Learning Approach
by Diogo Cardoso, António Ramos Silva and Nuno Correia
Processes 2026, 14(4), 609; https://doi.org/10.3390/pr14040609 - 10 Feb 2026
Viewed by 995
Abstract
Automated Fiber Placement (AFP) is a critical process in composite manufacturing, where precise fiber tow placement is essential for achieving high-quality and high-performance engineering components. However, deviations in process variables frequently lead to defects such as gaps and overlaps, which can compromise structural [...] Read more.
Automated Fiber Placement (AFP) is a critical process in composite manufacturing, where precise fiber tow placement is essential for achieving high-quality and high-performance engineering components. However, deviations in process variables frequently lead to defects such as gaps and overlaps, which can compromise structural integrity. While various monitoring techniques exist, accurately predicting and understanding the formation of these defects from complex sensor data remains challenging. This work introduces a novel application of a Transformer-based deep learning architecture to enhance the estimation of gap widths in AFP. Leveraging a publicly available industrial AFP dataset, our methodology incorporates a customized positional encoding scheme to effectively integrate the critical spatial context of the tow layup process. The model’s predictive performance was evaluated, achieving a Mean Absolute Percentage Error (MAPE) of 1.04% and an R-squared (R2) value of 0.9143, demonstrating its capability for accurate gap width estimation. Furthermore, SHapley Additive exPlanations (SHAP) analysis was employed to assess the complex interplay between sources of manufacturing process variation. This study establishes the Transformer architecture as a promising and interpretable data-driven tool for AFP process monitoring. The results serve as a proof of concept for attention-based virtual metrology, offering a pathway towards deeper process understanding and defect mitigation. Full article
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33 pages, 1359 KB  
Review
Development of Functional Fermented Meat Products Using Agro-Food Byproducts
by Yavor Ivanov, Milka Atanasova and Tzonka Godjevargova
Processes 2026, 14(4), 602; https://doi.org/10.3390/pr14040602 - 9 Feb 2026
Viewed by 1073
Abstract
Fermented foods play an important role in human nutrition due to their probiotic properties, improved nutrient absorption and potential health benefits. The incorporation of various agro-food byproducts into them leads to the production of innovative functional foods with even better nutritional properties. In [...] Read more.
Fermented foods play an important role in human nutrition due to their probiotic properties, improved nutrient absorption and potential health benefits. The incorporation of various agro-food byproducts into them leads to the production of innovative functional foods with even better nutritional properties. In recent years, the application of industrial byproducts has become a hot spot of research, as they are rich in polyphenols, flavonoids, carotenoids, tocopherols, vitamins and anthocyanins, which provide high antioxidant capacity for foods. Among the most popular groups of fermented foods are meat products. The addition of agro-food byproduct powder or extracts to these traditional food products leads to an increase in their nutritional value and antioxidant capacity, a decrease in lipid oxidation and color change, inhibition of the growth of pathogenic microorganisms and the provision of health benefits. The use of these ingredients in the fermentation of meat products is considered to be a promising strategy in the development of new functional fermented meat products. This review will discuss the development of functional fermented meat products by incorporating agro-food byproducts, determining their optimal concentration, studying their impact on the fermentation of the meat products and on its properties and storage, as well as the health benefits of these functional products. Full article
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20 pages, 3324 KB  
Article
Integrating Emerging Digital Technologies into Circular Economy Practices
by Elena Simina Lakatos, Andreea Loredana Rhazzali, Umberto Pernice, Oana Bianca Panait (Berce), Felix H. Arion and Lucian-Ionel Cioca
Processes 2026, 14(3), 556; https://doi.org/10.3390/pr14030556 - 5 Feb 2026
Viewed by 954
Abstract
This study stems from the clear need to understand why and how organizations in Romania integrate emerging digital technologies into circular economy (CE) practices, given the critical role of this integration in improving resource efficiency and supporting sustainable business models. Data were collected [...] Read more.
This study stems from the clear need to understand why and how organizations in Romania integrate emerging digital technologies into circular economy (CE) practices, given the critical role of this integration in improving resource efficiency and supporting sustainable business models. Data were collected through a structured questionnaire applied to 149 organizations of different sizes, ranging from SMEs (fewer than 50 employees) to large corporations (over 500 employees), operating across multiple sectors, including agriculture, construction, security, services and research. The questionnaire assessed organizations’ familiarity with CE principles, their stage of CE implementation, and their adoption of digital technologies, including artificial intelligence (AI), Internet of Things (IoT), blockchain, cloud computing and robotics. The results indicate that most organizations are aware of the potential benefits of digital technologies, particularly in terms of resource efficiency, enhanced product traceability and support for sustainability goals. However, effective implementation remains quite limited in many cases due to inadequate or outdated infrastructure, lack of technical skills, and organizational resistance to changes. At the same time, the findings further reveal a growing strategic interest in digitalization: approximately 41% of SMEs and 59% of large organizations plan to increase investments in digitalization, primarily to improve sustainability performance and foster innovation. Overall, the study provides a comprehensive overview of the current state of digitalization in support of CE in Romania and proposes practical recommendations for organizations and decision-makers, highlighting both emerging opportunities and persistent barriers. Full article
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19 pages, 5059 KB  
Article
Antibacterial and Antibiofilm Activities of Croton pluriglandulosus Carn.-Torres & Riina. Essential Oil and Its Membrane-Disruptive Effects
by Gabriel Lucas Carvalho Melo, Ellen Araújo Malveira, Caroline Raquel de Souza Silva, Aluska Kelly A. Nunes, Wildson Max Barbosa da Silva, Selene Maia de Morais, Hélcio Silva dos Santos, Leandro Bezerra de Lima, Cynthia Cavalcanti de Albuquerque, Diego Nathan do Nascimento Souza, Edson Holanda Teixeira and Mayron Alves de Vasconcelos
Processes 2026, 14(3), 537; https://doi.org/10.3390/pr14030537 - 3 Feb 2026
Viewed by 471
Abstract
Antimicrobial resistance is a major global health concern, intensified by the misuse of antibiotics and the lack of new effective treatments. Bacteria capable of forming biofilms exhibit increased resistance, making infections more difficult to treat. This study evaluated the essential oil from Croton [...] Read more.
Antimicrobial resistance is a major global health concern, intensified by the misuse of antibiotics and the lack of new effective treatments. Bacteria capable of forming biofilms exhibit increased resistance, making infections more difficult to treat. This study evaluated the essential oil from Croton pluriglandulosus leaves (OCp) for its antibacterial and antibiofilm properties. The essential oil, obtained by hydrodistillation and analyzed by GC-MS, contained eucalyptol (24.11%), spathulenol (16.90%), α-pinene (11.76%), and caryophyllene oxide (10.07%) as main constituents. Antibacterial activity was determined by Minimum Inhibitory Concentration (MIC) and Minimum Bactericidal Concentration (MBC), with inhibition observed only for Staphylococcus aureus (MIC 10 mg/mL; MBC 5 mg/mL). OCp reduced biofilm biomass and CFUs in most strains, particularly in S. aureus and Escherichia coli. Scanning Electron Microscopy (SEM) and Confocal Laser Scanning Microscopy (CLSM) showed membrane damage in treated cells. Overall, OCp displayed promising antibacterial and antibiofilm potential, representing the first report of such activity for this essential oil. Full article
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16 pages, 3457 KB  
Article
Investigation of Polyhydroxybutyrate (PHB) Biodegradability in Alkaline Landfill Soil
by Takuya Tamazawa, Shakir Ali and Young-Cheol Chang
Processes 2026, 14(3), 533; https://doi.org/10.3390/pr14030533 - 3 Feb 2026
Viewed by 1132
Abstract
The increased production of bio-based plastics, such as polyhydroxybutyrate (PHB), raises the need for a thorough understanding of the fate of these materials in natural and controlled disposal environments, such as landfills. However, there is a paucity of knowledge regarding PHB biodegradation at [...] Read more.
The increased production of bio-based plastics, such as polyhydroxybutyrate (PHB), raises the need for a thorough understanding of the fate of these materials in natural and controlled disposal environments, such as landfills. However, there is a paucity of knowledge regarding PHB biodegradation at alkaline landfill sites containing incineration ash. This study aimed to investigate the biodegradability of PHB films in alkaline landfill soil (pH 9.7) and campus soil (pH 7). PHB biodegradation was much faster in campus soil (100%) than in alkaline landfill soil (65.2%) after 63 days. Bioaugmentation with Ralstonia insidiosa C1 (Ralstonia sp. C1) enhanced the PHB biodegradability from 13.6% to 35% in landfill soil and from 26.6% to 79.8% in campus soil. Landfill soil had a bacterial CFU of (2.1 × 106) and fungal CFU of (7.3 × 103), which is significantly lower than the bacterial CFU (4.4 × 108) and fungal CFU (1.1 × 107) in campus soil, thereby limiting the biomass required for effective PHB decomposition. Next-generation sequencing revealed that landfill soil lacks key PHB-degrading microbial genera that are normally found in soil, such as Ralstonia, Enterobacter, and Comamonas. In conclusion, PHB biodegradability is strongly affected by alkaline landfill soil, the control of which is the key to ensuring effective in situ bioplastic waste management. Full article
(This article belongs to the Special Issue Environmental Protection and Remediation Processes)
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28 pages, 2654 KB  
Article
Increasing Efficiency of Chemico-Technological Systems and Prevention of Accidents: Approaches, Models, Portfolios
by Gregory Yablonsky and Alexander Fedorov
Processes 2026, 14(3), 524; https://doi.org/10.3390/pr14030524 - 2 Feb 2026
Viewed by 614
Abstract
The aim of this work is to develop a beneficial methodology for improving the ecological and economic efficiency of chemico-technological systems (CTS). The problem is formulated as a control with a vector objective function that includes economic and environmental components. A practical approach [...] Read more.
The aim of this work is to develop a beneficial methodology for improving the ecological and economic efficiency of chemico-technological systems (CTS). The problem is formulated as a control with a vector objective function that includes economic and environmental components. A practical approach to enhancing the environmental and economic efficiency of CTS is presented. Some approaches to accident prevention including the application of a problem-oriented dynamic model are introduced. Extended Ecological–Technological Portfolios have been developed. These Portfolios represent simplified visual models aiming to increase the environmental and economic efficiency of the CTS. Portfolios allow for the identification of dependencies between technological faults and ecological criteria and enable the investigation of the impact of the concrete chemico-technological process on the environment. Based on the Portfolios, decisions can be made for improving the economic–ecological efficiency of CTS and the prevention of accidents. Ecological–Technological Matrices, which provide a generalized characterization of technological breakdowns, have been developed. A strategy for adjusting technological constraints, using Matrices and vector criteria, has been proposed. Portfolios and Matrices can be applied in data preparation to solve certain artificial intelligence tasks for increasing the environmental and economic efficiency of potentially hazardous CTS. Some examples are given, presenting the industrial control of ammonia synthesis, methane conversion, and chemical absorption of CO2. Full article
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18 pages, 2073 KB  
Article
Photoprotective Archaeosomes Made of Lipids Extracted with Bio-Solvents
by Yamila Roxana Simioni, Victoria Rebeca Dana González Epelboim, Gustavo Apezteguia, Leticia Herminia Higa, Eder Lilia Romero and Maria Jose Morilla
Processes 2026, 14(3), 499; https://doi.org/10.3390/pr14030499 - 31 Jan 2026
Viewed by 540
Abstract
Archaeal lipids are a source of new biomaterials for pharmaceutical and nanomedical applications; however, their classical extraction method relies on chloroform and methanol, toxic solvents that conflict with green chemistry principles. In this paper, we explore the performance of an eco-friendly method for [...] Read more.
Archaeal lipids are a source of new biomaterials for pharmaceutical and nanomedical applications; however, their classical extraction method relies on chloroform and methanol, toxic solvents that conflict with green chemistry principles. In this paper, we explore the performance of an eco-friendly method for the extraction of total lipids from the haloarchaea Halorubrum tebenquichense. Using the bio-solvents ethyl acetate and ethanol in a two-step procedure, a fraction of total lipids (135 ± 41 mg phospholipids and 1.1 ± 0.4 mg bacterioruberin (BR)/100 g cell paste) was obtained containing the same composition as that resulting from extraction with the classical solvents, as confirmed by electrospray ionization mass spectrometry, although with lower phospholipid (PL) content, thus with a higher proportion of bacterioruberin (BR/PL ratio 9.0 vs. 6.8 µg/mg). The extracted lipids were subsequently utilized for the preparation of archaeosomes, which were characterized by uniform size distribution (406 ± 137 nm, 0.63 ± 0.13 polydispersity index), colloidal stability, and negative ζ potential (−38.2 ± 5.4 mV). The photoprotective potential of these archaeosomes was determined for the first time in human keratinocyte (HaCaT) cells exposed to UVB irradiation (270 mJ/cm2). Treatment with archaeosomes significantly (p < 0.05) enhanced cell viability (from ~43 to ~80%), reduced intracellular ROS generation and proinflammatory cytokine release (TNF-α), and mitigated UVB-induced apoptosis compared to untreated controls, indicating effective cytoprotection. This study demonstrates that ethyl acetate–ethanol-based extraction offers an alternative for archaeal lipid recovery and highlights the potential of archaeosomes as natural photoprotective agents for skincare applications. Full article
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23 pages, 2208 KB  
Article
Dye Photocatalytic Degradation and Water Treatment Using Biosynthetic ZnO Nanoparticles Produced Using Annatto Tree Leaf Extract
by Aparecido de J. Bernardo, Andrei N. G. Dabul, Moudo Thiam, Vanessa O. A. Pellegrini, Mariana A. Silva, Sreedevi Vallabhapurapu, Sachin Desarada, Vijaya Srinivasu Vallabhapurapu, Carla R. Fontana and Igor Polikarpov
Processes 2026, 14(3), 459; https://doi.org/10.3390/pr14030459 - 28 Jan 2026
Cited by 1 | Viewed by 1046
Abstract
The biosynthesis of zinc oxide nanoparticles (ZnO NPs) using plant extracts offers several important advantages, including low residue generation, reduced costs, and potentially faster production as compared to traditional chemical methods. In this study, for the first time, ZnO NPs were biosynthesized using [...] Read more.
The biosynthesis of zinc oxide nanoparticles (ZnO NPs) using plant extracts offers several important advantages, including low residue generation, reduced costs, and potentially faster production as compared to traditional chemical methods. In this study, for the first time, ZnO NPs were biosynthesized using an annatto plant (Bixa orellana) leaf extract and characterized using a range of analytical techniques, including scanning electron microscopy, X-ray diffraction, energy-dispersive X-ray spectroscopy, ultraviolet–visible and Fourier transform infrared spectroscopies, thermogravimetric analysis, and point of zero charge measurements, thus ensuring a comprehensive elucidation of their physicochemical properties. Subsequently, photodegradation of methylene blue (MB) dye using the biosynthesized ZnO NPs was successfully demonstrated. The photodegradation studies showed that the ZnO NPs were capable of decomposing over 95% of MB after 110 min of UV irradiation. In addition, the potential application of ZnO NPs for water disinfection was evaluated by assessing their ability to eliminate microbial pathogens. Furthermore, cell-free singlet oxygen and intracellular ROS detection assays were performed to investigate the NP antibacterial molecular mechanisms. Overall, our results reveal that the ZnO NPs exhibit excellent potential for photodegradation applications and may contribute to the development of more effective and sustainable solutions for water treatment and quality control. Full article
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14 pages, 1779 KB  
Article
Electro-Reforming of Biomass Gasification Tar with Simultaneous Hydrogen Evolution
by Umberto Calice, Francesco Zimbardi, Nadia Cerone and Vito Valerio
Processes 2026, 14(3), 444; https://doi.org/10.3390/pr14030444 - 27 Jan 2026
Viewed by 737
Abstract
In this study, an electrochemical valorization strategy on liquid byproducts from hazelnut shell gasification was developed to couple waste remediation with energy-efficient hydrogen production. The aqueous phase, rich in organic compounds, is processed in an anion exchange membrane (AEM) cell, where pure hydrogen [...] Read more.
In this study, an electrochemical valorization strategy on liquid byproducts from hazelnut shell gasification was developed to couple waste remediation with energy-efficient hydrogen production. The aqueous phase, rich in organic compounds, is processed in an anion exchange membrane (AEM) cell, where pure hydrogen evolved at the cathode while organic pollutants are oxidized at the anode. First, the feedstock is thoroughly characterized using gas chromatography–mass spectrometry (GC-MS), identifying a complex matrix of water-soluble aromatic compounds such as phenols, catechols, and other aromatics compounds, with concentrations reaching up to 2.9 g/kg for catechols. Then, the electro-reforming process is optimized using Nickel oxide–hydroxide (Ni(O)OH) electrodes with a loading of 0.75 mg/cm2. This methodology relies on the favorable thermodynamics of organic oxidation, which requires a lower onset potential (0.4 V) compared to the oxygen evolution reaction (OER) observed in the alkaline control (0.52 V), and the low overpotential of the Nickel oxide–hydroxide electrode towards the oxidized species. Consequently, the organic load undergoes progressive oxidation into hydrophilic and less bioaccumulating species and carbon dioxide, allowing for the simultaneous generation of pure hydrogen at the cathode at a reduced cell voltage. Elevated stability was observed, with a substantial abatement—78% of the initial organic load—of organic compounds achieved over 80 h at a fixed cell voltage of 0.5 V, and a specific energy consumption for hydrogen production of 38.5 MJkgH21. This represents a step forward in the development of technologies that reduce the energy intensity of hydrogen generation while valorizing biomass gasification residues. Full article
(This article belongs to the Topic Advances in Hydrogen Energy)
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16 pages, 3500 KB  
Article
Fluorescence and Phosphorescence Assay of β-D-Glucans from Basidiomycete Medicinal Mushrooms
by Amin Karmali
Processes 2026, 14(3), 442; https://doi.org/10.3390/pr14030442 - 27 Jan 2026
Cited by 1 | Viewed by 607
Abstract
Basidiomycete mushrooms contain complex β-D-glucans which act as immunomodulator, immune stimulants and anti-cancer agents, which can be either free or bound to proteins. The present report consists of a novel and intrinsic synchronous fluorescence and phosphorescence assay method for β-D-glucans. This analytical technique [...] Read more.
Basidiomycete mushrooms contain complex β-D-glucans which act as immunomodulator, immune stimulants and anti-cancer agents, which can be either free or bound to proteins. The present report consists of a novel and intrinsic synchronous fluorescence and phosphorescence assay method for β-D-glucans. This analytical technique was carried out by a spectrofluorometer in the range of 250 to 750 nm with a Δλ range of 5–30 nm which exhibited peaks at 492, 540 and 550 nm by using β-D-glucan from Euglena gracilis as a standard. A micro and high-throughput method based on a microplate fluorescence reader was devised with a excitation and emissions λ of 420 nm and 528 nm, respectively. This assay method revealed some advantages over the reported colorimetric methods, since it is a non-destructive assay method of β-D-glucans in samples with a linearity range of 0–14 μg/well, correlation coefficient (r2) of 0.9961, LOD of 0.973 μg/well, LOQ of 2.919 μg/well, greater sensitivity, fast, a high-throughput method and very economical. β-D-glucans of several mushrooms (i.e., Poria coccus, Auricularia auricula, Ganoderma lucidium, Pleurotus ostreatus, Cordyceps sinensis, Agaricus blazei, Polyporus umbellatus, Inonotus obliquee) were purified by using a sequence of various solvent extractions, quantified by either spectrofluorometer or fluorescence microtiter plate reader assay and compared with Congo red assay method. Three-dimensional spectra measurements were carried out on β-D-glucans from commercial sources and medicinal mushroom strains. FTIR spectroscopy was selected to investigate the structural properties of β-D-glucans in these mushroom samples. Therefore, the present assay method is simple, fast, cheap and non-destructive for β-D-glucans from medicinal mushrooms as well as from commercial sources. Full article
(This article belongs to the Special Issue Research of Bioactive Synthetic and Natural Products Chemistry)
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14 pages, 2614 KB  
Article
Polyvinyl Chloride-Based Coordination Polymer as Membrane for Phenol Detection
by Anemona-Mariana Cornea, Milica Tara-Lunga Mihali, Ildiko Buta, Valentin Maranescu, Aurelia Visa, Alina Bora and Nicoleta Plesu
Processes 2026, 14(3), 435; https://doi.org/10.3390/pr14030435 - 26 Jan 2026
Viewed by 445
Abstract
The investigation primarily focuses on synthesizing Polyvinyl Chloride (PVC)-coordination polymer (CP) polymeric membranes that employ L-Cu-NO3 (1[Cu3L2(NO3)]NO3·2MeOH·2H2O based on the Schiff base H2L, where H2L [...] Read more.
The investigation primarily focuses on synthesizing Polyvinyl Chloride (PVC)-coordination polymer (CP) polymeric membranes that employ L-Cu-NO3 (1[Cu3L2(NO3)]NO3·2MeOH·2H2O based on the Schiff base H2L, where H2L stands for N,N’-bis[(2-hydroxybenzilideneamino)-propyl]-piperazine)) as a coordination polymer. The membrane’s capacity to hold moisture is greatly improved by the addition of CPs. The water contact angle dropped from 73.4° for the PVC to about 71° for the composite membrane, indicating that the CP–PVC polymer interactions improved the hydrophilicity. Impedance spectroscopy (EIS) was used to determine the membranes response to the tested concentrations of phenol solution at pH 9.11 in the concentration range of 10−10 to 10−2 mol·L−1. A PVC membrane with a 0.6 wt% L-Cu-NO3 deposit on a Cu electrode yields the best response. Between 10−8 and 10−5 mol·L−1 phenol, a linear dependence was found. The detection limit was 4.64 × 10−8 mol·L−1. Full article
(This article belongs to the Section Pharmaceutical Processes)
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33 pages, 5423 KB  
Article
Copper Coordination Compounds as Corrosion-Resistant Materials for Seawater Electrolysis
by Markus Bergendahl, Iván Brito, Luis Cáceres, Alvaro Soliz, Víctor M. Jiménez-Arévalo, Danny Guzman, Pedro Zamora, Norman Toro and Felipe M. Galleguillos Madrid
Processes 2026, 14(3), 423; https://doi.org/10.3390/pr14030423 - 25 Jan 2026
Viewed by 757
Abstract
Seawater electrolysis offers a promising route for sustainable hydrogen production in coastal areas, leveraging solar energy while reducing freshwater consumption. Yet, chloride-induced corrosion severely limits conventional electrodes such as titanium, which depend on passive titanium dioxide films and display minimal hydrogen evolution reaction [...] Read more.
Seawater electrolysis offers a promising route for sustainable hydrogen production in coastal areas, leveraging solar energy while reducing freshwater consumption. Yet, chloride-induced corrosion severely limits conventional electrodes such as titanium, which depend on passive titanium dioxide films and display minimal hydrogen evolution reaction activity (|i0,H2| ≈ 0.001–0.01 A/m2). Here, we report for the first time the use of copper-based coordination compounds—a triazole-derived polymer (CCCu) and a Prussian Blue Analogue (CuHCF)—as dual-function electrodes combining corrosion resistance with electrocatalytic activity. Structural integrity was verified by FTIR, TGA, XRD, and SEM/EDS analyses. Electrochemical tests in 0.5 M NaCl, interpreted using mixed potential theory, revealed corrosion potentials (Ecorr) of −40 mV versus Standard Hydrogen Electrode (CuHCF) and −23 mV versus Standard Hydrogen Electrode (CCCu), and corrosion current densities of 0.259 and 0.379 A/m2, respectively. Both exhibited hydrogen evolution reaction exchange current densities significantly higher than titanium (0.019 A/m2 for CuHCF and 0.062 A/m2 for CCCu). CuHCF achieved a Tafel slope of 222 mV/dec, comparable to NiMoP alloys and carbon steel. Complementary density functional theory calculations elucidated how metal–ligand interactions and electronic redistribution govern both catalytic performance and degradation. These findings introduce a new concept of semi-electrocatalysts, where copper coordination compounds act as structurally adaptive, low-cost materials bridging corrosion resistance and hydrogen evolution in seawater systems. Full article
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17 pages, 834 KB  
Article
Grape Pomace Flour as a Sustainable Ingredient in Cookie Formulation for Fiber, Free, and Bound Phenols Improvement
by Carlos E. Galindo-Corona, Gloria A. Martinez-Medina, Ricardo Gómez-García, Ayerim Y. Hernández-Almanza, Jorge Armando Meza-Velázquez, Martha Lizeth Quintana-Burciaga, Mariana Mesta-Corral, Cristian Torres-León and Nathiely Ramírez-Guzmán
Processes 2026, 14(3), 410; https://doi.org/10.3390/pr14030410 - 24 Jan 2026
Cited by 1 | Viewed by 1053
Abstract
This study aimed to evaluate the substitution of wheat flour (WF) for grape (Vitis vinifera L.) pomace (GP) on cookie formulation. The techno-functional properties of GP flour (GPF) were characterized, and cookie formulations containing 15% (C15) and 20% (C20) GPF were developed. [...] Read more.
This study aimed to evaluate the substitution of wheat flour (WF) for grape (Vitis vinifera L.) pomace (GP) on cookie formulation. The techno-functional properties of GP flour (GPF) were characterized, and cookie formulations containing 15% (C15) and 20% (C20) GPF were developed. To evaluate the antioxidant and functional potential, free (FPF, soluble phenols) and bound phenolic fraction (BPF, insoluble phenols) were extracted. The total phenolic content (TPC) and antioxidant potential (ABTS and DPPH assays) were measured. The GPF shows differences in oil and water retention, non-foaming properties, and non-significant differences in swelling capacity compared to WF. C15 and C20 show L* values from 27.9 to 36.2, b* values from 2.22 to 2.64, and a* values from 8.84 to 10.49. GPF addition elevates ash and fiber content by 3.5–4.2 and 14–31.6 times. GPF cookie (C15) exhibited a significantly higher TPC compared to WF. Although the FPF fraction in the cookies was higher compared to BPF, the contribution of BPF to antioxidant activity was high (DPPH = 29.9%, ABTS = 16.3%) compared to FPF (DPPH = 26.3%, ABTS = 20.3%). Given that FPF is traditionally the only antioxidant fraction measured, the antioxidant potential of incorporating grape by-products is being underestimated; this is the first report of this in a cookie. Full article
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19 pages, 59527 KB  
Article
Hierarchical Control System for a Multi-Port, Bidirectional MMC-Based EV Charging Station: A Model-in-the-Loop Validation
by Tomas Ravet, Cristobal Rodriguez, Matias Diaz, Daniel Velasquez, Roberto Cárdenas and Pat Wheeler
Processes 2026, 14(2), 384; https://doi.org/10.3390/pr14020384 - 22 Jan 2026
Viewed by 617
Abstract
The increasing demand for high-power electric vehicle charging systems with Vehicle-to-Grid (V2G) capability highlights the need for modular, scalable power converters. This paper proposes a hierarchical control strategy for a high-power, multi-port electric vehicle charging station. The system, based on a Series-Parallel Modular [...] Read more.
The increasing demand for high-power electric vehicle charging systems with Vehicle-to-Grid (V2G) capability highlights the need for modular, scalable power converters. This paper proposes a hierarchical control strategy for a high-power, multi-port electric vehicle charging station. The system, based on a Series-Parallel Modular Multilevel Converter (SP-MMC) with isolated modules, is managed by a coordinated control strategy that integrates proportional-integral-resonant regulators, nearest-level control with voltage sorting, and single-phase-shifted modulation. The proposed system enables simultaneous, independent regulation of multiple bidirectional, isolated direct current ports while maintaining grid-side power quality and internal variables of the SP-MMC. The proposed control is validated using real-time Model-In-the-Loop (MIL) simulations that include sequential port activation, bidirectional power flow, and charging operation. MIL results demonstrate stable operation with controlled DC-link voltage ripple, accurate per-port current tracking, and near-unity grid power factor under multi-port operation. Full article
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17 pages, 1272 KB  
Article
Technoeconomic and Life Cycle Analysis of a Novel Catalyzed Process for Producing Ethylene from Waste Plastic
by Xiaoyan Wang, Md. Emdadul Haque, Chunlin Luo, Jianli Hu and Srinivas Palanki
Processes 2026, 14(2), 333; https://doi.org/10.3390/pr14020333 - 17 Jan 2026
Cited by 1 | Viewed by 694
Abstract
Polyethylene is the most used plastic in the world, and over 90% of this plastic is ultimately disposed of in landfills or released into the environment, leading to severe ecological implications. In this research, the technoeconomic feasibility of upcycling low-density polyethylene (LDPE) to [...] Read more.
Polyethylene is the most used plastic in the world, and over 90% of this plastic is ultimately disposed of in landfills or released into the environment, leading to severe ecological implications. In this research, the technoeconomic feasibility of upcycling low-density polyethylene (LDPE) to produce ethylene is studied. The catalytic conversion of LDPE to ethylene is considered in microwave heating mode and Joule heating mode. Experimental data is obtained under conditions where most of the upcycled products are in the gas phase. A flowsheet is developed that produces industrial quantities of ethylene for both heating modes. A technoeconomic analysis and a life cycle analysis are conducted and compared with the traditional ethane cracking process for producing ethylene. Simulation results indicate that the upcycling system exhibits a lower capital expenditure and a comparable operating expenditure relative to conventional ethane steam cracking while generating additional valuable co-products, such as propylene and aromatic hydrocarbons, leading to a higher net present value potential. Sensitivity analyses reveal that the electricity price has the most significant impact on both the net present value and levelized cost of production, followed by the low-density polyethylene feedstock cost. Life-cycle assessment reveals a substantial reduction in greenhouse-gas emissions in the upcycled process compared to the fossil-based ethane steam-cracking route, primarily due to the use of renewable electricity, the lower reaction temperature that reduces utility demand, and the use of plastic waste as the feedstock. Overall, the proposed process demonstrates strong potential for the sustainable production of ethylene from waste LDPE. Full article
(This article belongs to the Section Chemical Processes and Systems)
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14 pages, 6663 KB  
Article
Study on the Diffusion and Atomic Mobility of Alloying Elements in the β Phase of the Ti-Cr-Nb Ternary System
by Danya Shen, Jingmin Liu, Wenqing Zhao, Junfeng Wu, Maohua Rong, Jiang Wang, Hongyu Zhang, Ligang Zhang and Libin Liu
Processes 2026, 14(2), 331; https://doi.org/10.3390/pr14020331 - 17 Jan 2026
Viewed by 412
Abstract
Diffusion-controlled processes play a critical role in the heat treatment and microstructural homogenization of β-titanium alloys containing multiple β-stabilizing elements. Adding β-phase stabilizing elements like Cr and Nb to titanium alloys can significantly improve the high-temperature strength and creep performance of the alloy. [...] Read more.
Diffusion-controlled processes play a critical role in the heat treatment and microstructural homogenization of β-titanium alloys containing multiple β-stabilizing elements. Adding β-phase stabilizing elements like Cr and Nb to titanium alloys can significantly improve the high-temperature strength and creep performance of the alloy. Their diffusion coefficients can be used to predict the risk of softening and creep failure in high-temperature components caused by diffusion. However, reliable diffusion kinetic data for the β phase in the Ti–Cr–Nb ternary system remain scarce, limiting quantitative process modeling and simulation. In this study, diffusion behavior in the BCC (β) region of the Ti–Cr–Nb system was investigated using diffusion couples combined with CALPHAD-based kinetic modeling. Twelve sets of diffusion couples were prepared and annealed at 1373 K for 48 h, 1423 K for 36 h, and 1473 K for 24 h. The corresponding composition–distance profiles were measured by electron probe microanalysis. Composition-dependent interdiffusion coefficients and atomic mobility parameters were determined using the numerical inverse method. The results revealed temperature and composition dependence of the main interdiffusion coefficients, with Nb exhibiting a stronger influence than Cr. The evaluated kinetic parameters provide an effective kinetic description for diffusion-controlled process simulations. Full article
(This article belongs to the Section Materials Processes)
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29 pages, 4949 KB  
Article
Multivariate Statistical Insights into Copper Adsorption by Graphene Oxide-Based Adsorbents
by Jovana Pešić Bajić, Marko Šolić, Jasmina Nikić, Branko Kordić, Tamara Apostolović and Malcolm Watson
Processes 2026, 14(2), 315; https://doi.org/10.3390/pr14020315 - 16 Jan 2026
Cited by 1 | Viewed by 797
Abstract
Copper contamination in aquatic environments poses significant ecological and health risks, necessitating efficient and resilient treatment strategies. In this study, graphene oxide (GO) and magnetic graphene oxide (MGO) were synthesized and comprehensively evaluated for Cu(II) removal using an integrated multivariate approach combining kinetic [...] Read more.
Copper contamination in aquatic environments poses significant ecological and health risks, necessitating efficient and resilient treatment strategies. In this study, graphene oxide (GO) and magnetic graphene oxide (MGO) were synthesized and comprehensively evaluated for Cu(II) removal using an integrated multivariate approach combining kinetic and isotherm modelling, Response Surface Methodology (RSM), and advanced statistical analyses. Both adsorbents achieved high removal efficiencies (>90%) under optimized conditions, with Langmuir capacities of 59.2 mg g−1 for GO and 40.1 mg g−1 for MGO. Kinetic modelling confirmed reaction-controlled adsorption, while Freundlich isotherms highlighted heterogeneous surface binding. RSM identified pH as the dominant factor governing removal efficiency, with significant interactions among pH, Cu(II), and DOC reflecting competitive matrix effects. Principal Component Analysis (PCA) revealed that GO performance is strongly influenced by solution chemistry, whereas MGO exhibits reduced sensitivity due to modified physicochemical properties. FTIR analysis confirmed that adsorption proceeds primarily through electrostatic attraction and inner-sphere complexation, with Fe–O sites contributing to MGO’s enhanced affinity. Regeneration studies demonstrated superior reusability of MGO, which retained ~64% efficiency after five cycles compared to ~52% for GO. Collectively, these multivariate and mechanistic insights identify MGO as a more robust, versatile, and regenerable sorbent for Cu(II) removal under realistic water-matrix conditions. Full article
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13 pages, 4926 KB  
Article
Novel Ultrafast Synthesis of Perovskites via Commercial Laser Engraving
by Pedro Piza-Ruiz, Griselda Mendoza-Gómez, Maria Luisa Camacho-Rios, Guillermo Manuel Herrera-Perez, Luis Carlos Rodriguez Pacheco, Kevin Isaac Contreras-Vargas, Daniel Lardizábal-Gutiérrez, Antonio Ramírez-DelaCruz and Caleb Carreno-Gallardo
Processes 2026, 14(2), 327; https://doi.org/10.3390/pr14020327 - 16 Jan 2026
Viewed by 734
Abstract
We present a rapid, energy-efficient, and ecofriendly route for the synthesis of alkaline earth titanate perovskites—CaTiO3, SrTiO3, and BaTiO3—using an affordable, commercially available CO2 laser engraver, commonly found in makerspaces and small-scale workshops. The method involves [...] Read more.
We present a rapid, energy-efficient, and ecofriendly route for the synthesis of alkaline earth titanate perovskites—CaTiO3, SrTiO3, and BaTiO3—using an affordable, commercially available CO2 laser engraver, commonly found in makerspaces and small-scale workshops. The method involves direct laser irradiation of compacted pellets composed of low-cost, abundant, and non-toxic precursors: TiO2 and alkaline earth carbonates (CaCO3, SrCO3, BaCO3). CaTiO3 and BaTiO3 were synthesized with phase purities exceeding 97%, eliminating the need for conventional high-temperature furnaces or prolonged thermal treatments. X-ray diffraction (XRD) coupled with Rietveld refinement confirmed the formation of orthorhombic CaTiO3 (Pbnm), cubic SrTiO3 (Pm3m), and tetragonal BaTiO3 (P4mm). Raman spectroscopy independently corroborated the perovskite structures, revealing vibrational fingerprints consistent with the expected crystal symmetries and Ti–O bonding environments. All samples contained only small amounts of unreacted anatase TiO2, while BaTiO3 exhibited a partially amorphous fraction, attributed to the sluggish crystallization kinetics of the Ba–Ti system and the rapid quenching inherent to laser processing. Transmission electron microscopy (TEM) revealed nanoparticles with average sizes of 50–150 nm, indicative of localized melting followed by ultrafast solidification. This solvent-free, low-energy, and highly accessible approach, enabled by widely available desktop laser systems, demonstrates exceptional simplicity, scalability, and sustainability. It offers a compelling alternative to conventional ceramic processing, with broad potential for the fabrication of functional oxides in applications ranging from electronics to photocatalysis. Full article
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22 pages, 5388 KB  
Article
Mass Deposition Rates of Carbon Dioxide onto a Cryogenically Cooled Surface
by Martin Jan Tuinier, Wout Jacob René Ververs, Danica Tešić, Ivo Roghair and Martin van Sint Annaland
Processes 2026, 14(2), 271; https://doi.org/10.3390/pr14020271 - 12 Jan 2026
Viewed by 541
Abstract
The rates of CO2 mass deposition onto cryogenically cooled surfaces are crucial for CO2 removal processes that rely on cryogenics. A dedicated experimental setup was constructed to measure CO2 mass deposition rates under controlled conditions. Experiments were carried out with [...] Read more.
The rates of CO2 mass deposition onto cryogenically cooled surfaces are crucial for CO2 removal processes that rely on cryogenics. A dedicated experimental setup was constructed to measure CO2 mass deposition rates under controlled conditions. Experiments were carried out with both pure CO2 and CO2/N2 mixtures, growing frost layers up to 8 mm thick. Results demonstrated that heat transfer through the frost layer significantly slows down the mass deposition process. Furthermore, it was found that the addition of N2 to the gas phase has a considerable influence on mass deposition rates, because it introduces an additional mass transfer resistance toward the frost surface. To describe the experimentally observed behavior, a frost growth model based on mass and energy balances was developed. Expressions for the frost density as a function of the frost temperature and for the effective frost conductivity as a function of the frost density were derived and implemented in the model. When accounting for drift fluxes, the model accurately captures the behavior observed in experiments. The findings of this work highlight the significant impact of heat transfer limitations on processes that accumulate a thick solid CO2 layer, such as continuously cooled heat exchangers. Conversely, technologies like cryogenically refrigerated packed beds do not develop a thick solid CO2 layer; calculations showed that a frost layer of 3.24·10−5 m is formed, resulting in a Biot number well below 0.01, indicating that heat transfer in the frost layer is not limiting. Full article
(This article belongs to the Section Chemical Processes and Systems)
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39 pages, 10403 KB  
Article
High-Temperature Degradation of Hastelloy C276 in Methane and 99% Cracked Ammonia Combustion: Surface Analysis and Mechanical Property Evolution at 4 Bar
by Mustafa Alnaeli, Burak Goktepe, Steven Morris and Agustin Valera-Medina
Processes 2026, 14(2), 235; https://doi.org/10.3390/pr14020235 - 9 Jan 2026
Viewed by 617
Abstract
This study examines the high-temperature degradation of Hastelloy C276, a corrosion-resistant nickel-based alloy, during exposure to combustion products generated by methane and 99% cracked ammonia. Using a high-pressure optical combustor (HPOC) at 4 bar and exhaust temperatures of 815–860 °C, standard tensile specimens [...] Read more.
This study examines the high-temperature degradation of Hastelloy C276, a corrosion-resistant nickel-based alloy, during exposure to combustion products generated by methane and 99% cracked ammonia. Using a high-pressure optical combustor (HPOC) at 4 bar and exhaust temperatures of 815–860 °C, standard tensile specimens were exposed for five hours to fully developed post-flame exhaust gases, simulating real industrial turbine or burner conditions. The surfaces and subsurface regions of the samples were analysed using scanning electron microscopy (SEM; Zeiss Sigma HD FEG-SEM, Carl Zeiss, Oberkochen, Germany) and energy-dispersive X-ray spectroscopy (EDX; Oxford Instruments X-MaxN detectors, Oxford Instruments, Abingdon, United Kingdom), while mechanical properties were evaluated by tensile testing, and the gas-phase compositions were tracked in detail for each fuel blend. Results show that exposure to methane causes moderate oxidation and some grain boundary carburisation, with localised carbon enrichment detected by high-resolution EDX mapping. In contrast, 99% cracked ammonia resulted in much more aggressive selective oxidation, as evidenced by extensive surface roughening, significant chromium depletion, and higher oxygen incorporation, correlating with increased NOx in the exhaust gas. Tensile testing reveals that methane exposure causes severe embrittlement (yield strength +41%, elongation −53%) through grain boundary carbide precipitation, while cracked ammonia exposure results in moderate degradation (yield strength +4%, elongation −24%) with fully preserved ultimate tensile strength (870 MPa), despite more aggressive surface oxidation. These counterintuitive findings demonstrate that grain boundary integrity is more critical than surface condition for mechanical reliability. These findings underscore the importance of evaluating material compatibility in low-carbon and hydrogen/ammonia-fuelled combustion systems and establish critical microstructural benchmarks for the anticipated mechanical testing in future work. Full article
(This article belongs to the Special Issue Experiments and Diagnostics in Reacting Flows)
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19 pages, 3161 KB  
Article
Pressure-Dependent Microbial Oil Production with Cutaneotrichosporon oleaginosus Converting Lignocellulosic Hydrolysate
by Fabian Herrmann, Nila Kazemian, Emelie Petzel and Dirk Weuster-Botz
Processes 2026, 14(2), 228; https://doi.org/10.3390/pr14020228 - 8 Jan 2026
Cited by 1 | Viewed by 773
Abstract
Microbial lipid production from renewable carbon sources, particularly lignocellulosic hydrolysates, is a promising alternative to plant-derived oils and fats for food applications, as it can minimize the land use by utilizing agricultural wastes and byproducts from food production. In this context, a standard [...] Read more.
Microbial lipid production from renewable carbon sources, particularly lignocellulosic hydrolysates, is a promising alternative to plant-derived oils and fats for food applications, as it can minimize the land use by utilizing agricultural wastes and byproducts from food production. In this context, a standard approach to prevent oxygen limitation at reduced air gassing rates during long-term aerobic microbial processes is to operate bioreactors at increased pressure for elevating the gas solubility in the fermentation broth. This study investigates the effect of absolute pressures of up to 2.5 bar on the conversion of the carbon sources (glucose, xylose, and acetate), growth, and lipid biosynthesis by Cutaneotrichosporon oleaginosus converting a synthetic nutrient-rich lignocellulosic hydrolysate at low air gassing rates of 0.1 vessel volume per minute (vvm). Increasing pressure delayed xylose uptake, reduced acetic acid consumption, and reduced biomass formation. Lipid accumulation decreased with increasing pressure, except for fermentations at 1.5 bar, which achieved a maximum lipid content of 83.6% (±1.6, w/w) (weight per weight in %). At an absolute pressure of 1.5 bar, a lipid yield from glucose, xylose, and acetic acid of 38% (w/w) was reached after 6 days of fermentation. The pressure sensitivity of C. oleaginosus may pose challenges on an industrial scale due to the dynamic changes in pressure when the yeast cells pass through the bioreactor. Increasing liquid heights in full-scale bioreactors will result in increased hydrostatic pressures at the bottom, substantially reducing lipid yields, e.g., to only 23% (w/w) at 2.0–2.5 bar, as shown in this study. However, further scale-up studies with dynamic pressure regimes (1–2.5 bar) may help to evaluate scale-up feasibility. Full article
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18 pages, 6462 KB  
Article
Effect of Different Impeller Types on Mixing Efficiency in Mechanically Stirred Tanks with Tubular Baffles
by Jesús Eduardo Lugo Hinojosa, Juan Antonio Yáñez Varela, Alejandro Alonzo García, Gabriela Rivadeneyra Romero and Sergio Alejandro Martínez Delgadillo
Processes 2026, 14(2), 225; https://doi.org/10.3390/pr14020225 - 8 Jan 2026
Cited by 1 | Viewed by 1686
Abstract
Efficient mixing in stirred tanks is essential for chemical and biochemical processes. Tubular baffles offer potential energy savings and multifunctionality (e.g., as heat exchangers); however, their interaction with common impeller types is not well understood. This study uses computational fluid dynamics (CFD) simulations [...] Read more.
Efficient mixing in stirred tanks is essential for chemical and biochemical processes. Tubular baffles offer potential energy savings and multifunctionality (e.g., as heat exchangers); however, their interaction with common impeller types is not well understood. This study uses computational fluid dynamics (CFD) simulations to evaluate the hydrodynamic performance of a novel tubular baffle design compared to conventional flat baffles with three impellers: a Rushton turbine (RT), a pitched blade turbine (PBT), and a hydrofoil (HE3). Dimensionless analysis (power number, NP; and pumping number, NQ), flow visualization, and vorticity dynamics were employed. The results show that, by attenuating large-scale recirculation, tubular baffles reduce power consumption by 64%, 13%, and 23% for the HE3, PBT, and RT, respectively. However, the HE3 impeller experienced a 30% decrease in pumping capacity, which confined the flow to the lower tank. The PBT showed a 10% increase in NQ and intensified bottom circulation. The RT uniquely generated distributed, high-intensity turbulence along the baffle height while maintaining its characteristic dual-loop structure. The analysis critiques the local pumping efficiency metric and advocates for a global flow assessment. The HE3 is optimal for efficient bulk blending at low power; the PBT is optimal for strong bottom circulation processes; and the RT is optimal for applications requiring enhanced interfacial processes, where baffles serve a dual function. This work provides a framework for selecting energy-efficient agitation systems by coupling impeller performance with global tank hydrodynamics. Full article
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13 pages, 2204 KB  
Article
Fast Cure of Bone Cement Based on Poly(Methyl Methacrylate)/Hydroxyapatite Nanocomposite for Application in Cranioplasty
by Matheus Alves Coelho, Alexandre Malta Rossi and Marcos Lopes Dias
Processes 2026, 14(2), 213; https://doi.org/10.3390/pr14020213 - 7 Jan 2026
Viewed by 597
Abstract
Novel initiation systems for the production of poly(methyl methacrylate) (PMMA) bone cements based on low-toxicity tertiary amine initiators and hydroxyapatite nanoparticles were investigated. Bicomponent systems formed by a solid component containing PMMA and benzoyl peroxide (BPO) and a liquid component containing methylmethacrylate and [...] Read more.
Novel initiation systems for the production of poly(methyl methacrylate) (PMMA) bone cements based on low-toxicity tertiary amine initiators and hydroxyapatite nanoparticles were investigated. Bicomponent systems formed by a solid component containing PMMA and benzoyl peroxide (BPO) and a liquid component containing methylmethacrylate and low-toxicity aliphatic (dimethylamino-ethoxy-ethane) (DMEE) and aromatic (dimethylamino-benzaldehyde) (DMAB) tertiary amines were tested at two amine concentrations (0.75 and 3.75 wt%) and compared with the standard tertiary amine dimethyl-p-toluidine (DMT). The components were mixed in a 2:1 ratio (solid/liquid) for 60 s. Nanocomposites were prepared using nano-hydroxyapatite inserted into the PMMA-based polymer matrix at various concentrations between 1.0 and 3.75 wt%, aiming to increase the biocompatibility of bone cements applied in cranioplasty. The concentration of tertiary amines directly affects the reaction rate, and increasing the concentration accelerates the curing reaction. Thermal analyses (DSC and TGA) revealed that the produced polymers did not show significant changes in glass transition temperature (113 °C and 115 °C), nor in onset (150–158 °C) or peak degradation temperatures (353 °C and 355 °C). The reaction with the aliphatic amine proved to be slow, as no polymerization occurred within the time period stipulated in the study. However, drastic changes did take place when the cure occurred in the presence of nano-hydroxyapatite. The cure with DMAB (3.75 wt%) that presented an exothermic peak at 37 min (53 °C) showed a peak at 16 min (70 °C), and the cure with DMEE (3.75 wt%) a peak at 11 min (62.5 °C) after the addition of nano-hydroxyapatite. In conclusion, addition of nano-hydroxyapatite significantly influenced both the time and the temperature of cure reaction in all amines studied, expanding the possibility of using new initiators in polymerization systems for cranioplasty flaps. Full article
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35 pages, 20755 KB  
Article
Advancing Geothermal Energy Recovery Through Reactive Transport Modelling and Horizontal Well Analysis: A Case Study of Lithuanian Reservoirs
by Abdul Rashid Abdul Nabi Memon and Mayur Pal
Processes 2026, 14(2), 203; https://doi.org/10.3390/pr14020203 - 7 Jan 2026
Cited by 2 | Viewed by 417
Abstract
The study underpins the geothermal energy potential of Cambrian reservoirs in Lithuania, which utilizes the use of reactive transport modelling to examine how different reinjection temperatures and flow rates affect mineral changes. The results are then applied to design field development plans, using [...] Read more.
The study underpins the geothermal energy potential of Cambrian reservoirs in Lithuania, which utilizes the use of reactive transport modelling to examine how different reinjection temperatures and flow rates affect mineral changes. The results are then applied to design field development plans, using petroleum engineering methods such as horizontal wells and induced fracturing. The research study indicates that there are some changes in porosity and permeability over time due to mineral dissolution and precipitation because of injection rates, but no adverse effect of re-injection temperature was observed. Hence, a reinjection temperature of 40 °C is geochemically stable and suitable for long-term operation, with no significant effect on mineral behavior. Moreover, application of horizontal wells proves that there is a significant increase in water production and power (thermal) output due to improved reservoir exposure. Hydraulic fracturing further enhanced the performance and flow rates, concluding that, among all the sites studied, Nausodis demonstrated the highest thermal output, while Genciai showed the lowest potential due to limited reservoir temperature and productivity. Thus, research aims to improve power output by studying how well design, reinjection methods, and chemical reactions affect the reservoir, and it shows that using horizontal wells, fracturing, and proper reinjection temperature can help increase geothermal energy recovery in Lithuania. Full article
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14 pages, 1498 KB  
Article
Assessment of UHPC with Various Particle Distributions (q) and Low Cement Consumption
by Raduan Krause Lopes, Roberto Christ, Jéssica Fröhlich, Jayne Carlos Piovesan and Bernardo Tutikian
Processes 2026, 14(2), 181; https://doi.org/10.3390/pr14020181 - 6 Jan 2026
Viewed by 781
Abstract
Ultra-high-performance concrete (UHPC) has been increasingly adopted in applications requiring superior mechanical performance and high durability under aggressive environments. However, its large-scale use is still limited by the high binder content and the lack of a standardized mix design methodology. Among the existing [...] Read more.
Ultra-high-performance concrete (UHPC) has been increasingly adopted in applications requiring superior mechanical performance and high durability under aggressive environments. However, its large-scale use is still limited by the high binder content and the lack of a standardized mix design methodology. Among the existing approaches, particle packing-based mix design methods have shown the most promising results, optimizing the composite structure and enabling efficient material proportioning. This study aimed to evaluate the influence of the particle distribution coefficient (q = 0.20 and 0.25) and the cement consumption ratio (15%, 20%, and 25%) on achieving the lowest packing deviation index (PDI) values using a rational UHPC mix design method. The results indicated that increasing q allowed a reduction of up to 15% in cement content, corresponding to 106 kg/m3 less binder. In contrast, changes in cement consumption, which led to different PDI values for the same q, had a significant effect on compressive strength. Mixtures with 20% cement and consumption of 598 kg/m3 exhibited the lowest PDI values (180 and 190) and the highest 91-day compressive strengths (147.0 and 151.1 MPa). Fiber reinforcement improved toughness and post-elastic energy absorption capacity. Overall, UHPC with reduced cement content and high mechanical performance can be achieved using a rational mix design method when an appropriate q value is selected. Full article
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24 pages, 4047 KB  
Article
Optimization of an NH3-H2O Absorption Cooling System Using an Inverted Multivariate Function with Neural Networks and PSO
by Ulises Cruz-Jacobo, Roberto Agustin Conde-Gutiérrez, Wilfrido Rivera, Darío Colorado and José Camilo Jiménez-García
Processes 2026, 14(1), 177; https://doi.org/10.3390/pr14010177 - 5 Jan 2026
Cited by 1 | Viewed by 572
Abstract
Absorption systems offer a practical alternative to traditional compression systems, especially when low-grade heat sources are available. Their applications range from vaccine preservation to space conditioning, making performance optimization essential. This study employed a multivariate inverse artificial neural network with multiple parameters (ANNim-mp) [...] Read more.
Absorption systems offer a practical alternative to traditional compression systems, especially when low-grade heat sources are available. Their applications range from vaccine preservation to space conditioning, making performance optimization essential. This study employed a multivariate inverse artificial neural network with multiple parameters (ANNim-mp) to simultaneously enhance the cooling load and coefficient of performance in an experimental single-effect ammonia–water absorption cooling system. Optimization was carried out using particle swarm optimization. The results showed significant performance improvements: up to 100% in cooling load and 97% in COP when optimizing two variables. With four-variable optimization, improvements reached 98.7% and 106.7%, respectively. These results demonstrate the strong potential of the ANNim-mp approach in enhancing the efficiency of absorption cooling systems. Full article
(This article belongs to the Special Issue Application of Absorption Cycles in Renewable Energy)
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36 pages, 14020 KB  
Article
Improved Two-Stage Theta* Algorithm for Path Planning with Uncertain Obstacles in Unstructured Rescuing Environments
by Jingrui Zhang, Mengxin Zhou, Houde Liu, Xiaojun Zhu, Bin Lan and Zhenhong Xu
Processes 2026, 14(1), 167; https://doi.org/10.3390/pr14010167 - 4 Jan 2026
Cited by 1 | Viewed by 870
Abstract
Path planning aims to find a safe and efficient path from a starting point to an end point, and it has been well developed in fields such as robot navigation, autonomous driving, and intelligent decision systems. However, traditional path planning faces challenges in [...] Read more.
Path planning aims to find a safe and efficient path from a starting point to an end point, and it has been well developed in fields such as robot navigation, autonomous driving, and intelligent decision systems. However, traditional path planning faces challenges in an uncertain rescuing environment due to limited sensing range and a lack of accurate obstacle information. In order to address this issue, this paper proposes an improved two-stage Theta* algorithm for handling multi-probability obstacle scenarios in unstructured rescue environments. First, a global probability raster map is constructed by integrating historical maps and expert prediction maps with probability weights quantifying the uncertainty in the spatial and temporal distribution of obstacles. Second, a probability-sensitive heuristic function (PSHF) is designed, and a Sigmoid function is used to map the probability field of obstacles, thereby enabling limited penetration in low-risk areas and enforced avoidance in high-risk areas. Furthermore, a multi-stage line-of-sight detection optimization mechanism is proposed, which combines probability soft threshold penetration and backtracking verification to improve the noise robustness. Finally, a hierarchical planning architecture is constructed to separate global probabilistic guidance from local strict obstacle avoidance, ensuring both the global optimality and local adaptability of the path. Extensive simulation results in mine rescue scenarios demonstrate that the proposed method achieves lower path cost and fewer path nodes compared to traditional A*, Dijkstra, and Theta* algorithms, while significantly reducing local replanning overhead and maintaining stable performance across multiple uncertain environments. Full article
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26 pages, 1529 KB  
Article
Sustainable Valorization of Tsipouro Liquid Waste via Fermentation for Hericium erinaceus Biomass Production
by Eirini Stini, Ilias Diamantis, Stamatina Kallithraka, Seraphim Papanikolaou and Panagiota Diamantopoulou
Processes 2026, 14(1), 168; https://doi.org/10.3390/pr14010168 - 4 Jan 2026
Viewed by 854
Abstract
This study investigates the potential of tsipouro liquid waste (TLW) as a sustainable substrate for cultivating the edible–medicinal mushroom Hericium erinaceus under static liquid fermentation. TLW naturally contains high glycerol levels and significant quantities of phenolic compounds; therefore, five media (0–50% v/ [...] Read more.
This study investigates the potential of tsipouro liquid waste (TLW) as a sustainable substrate for cultivating the edible–medicinal mushroom Hericium erinaceus under static liquid fermentation. TLW naturally contains high glycerol levels and significant quantities of phenolic compounds; therefore, five media (0–50% v/v TLW) with varying phenolic concentrations and a standard initial glycerol level (~20 g/L) were prepared to simulate TLW-type substrates. Throughout fermentation, physicochemical parameters in the culture medium (pH, electrical conductivity, total sugars, free amino nitrogen, proteins, laccase activity, total phenolics, ethanol, glycerol) and biomass composition (intracellular polysaccharides, proteins, lipids, phenolic compounds, flavonoids, triterpenoids, antioxidant activity) were determined. Results showed that increasing TLW concentration enhanced biomass production and bioactive metabolite accumulation. The highest dry biomass (22.8 g/L) and protein (4.06 g/L) content were obtained in 50% v/v TLW, while maximum polysaccharides (6.8 g/L) occurred in 17% v/v TLW. Fungal growth led to a reduction of up to 74% in total phenolic content, indicating simultaneous bioremediation potential. Fruiting body formation—rare and uncommon in liquid cultures—occurred at the end of fermentation period. Fruiting bodies contained higher protein (24.5% w/w) and total phenolic compounds (13.36 mg GAE/g), whereas mycelium accumulated more polysaccharides (49% w/w). This study demonstrates that TLW can serve as a cost-effective, ecofriendly medium for producing high-value H. erinaceus biomass and bioactive metabolites, supporting circular bioeconomy applications in the alcoholic beverage sector. Full article
(This article belongs to the Special Issue Resource Utilization of Food Industry Byproducts)
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